Eu3+掺杂正硅酸钡锶(SrBaSiO4)荧光粉的制备及其发光性能

P. Chaudhari, Dilip B. Chaudhari, O. Mahajan
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引用次数: 0

摘要

采用高温改性固体扩散法制备了铕掺杂BaSrSiO4荧光粉。以碳酸锶SrCO3为原料,碳酸钡baco3和硅酸SiO3为原料制备BaSrSiO4荧光粉,并对其光学性能进行了研究。XRD分析表明SrCO3与SiO2粉体之间存在直接反应。利用Scherer公式从衍射的x射线峰展宽计算了粉末样品的晶粒尺寸。计算得到BaSrSiO4荧光粉的平均晶粒尺寸为25 nm。粉末的XRD谱图表明,BaSrSiO4为正交结构。研究了所得荧光粉的光致发光性能。根据失重量计算出了BaSrSiO4原料的转化率。铕掺杂BaSrSiO4荧光粉的CIE坐标分别为x=0.30和y=0.31。来自于Eu掺杂BaSrSiO4发射光谱的CIE色度图。该荧光粉具有显色性,是照明系统的重要候选荧光粉。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation and Luminescent Properties of Eu3+ Doped Barium Strontium Orthosilicate (SrBaSiO4) Phosphor
Europium doped BaSrSiO4 phosphors were prepared by high temperature modified solid state diffusion method. The starting materials Strontium carbonate SrCO3 Barium carbonate BaCO3and silicate SiO3 are used to prepare BaSrSiO4 Phosphor and its optical properties were studied. XRD analysis suggests direct reaction between SrCO3 and SiO2 powders. The crystallite size of powders samples were calculated from X-ray peak broadening of the diffraction using Scherer’s formula. The calculated average crystallite size of the BaSrSiO4 phosphor is 25 nm. The XRD patterns of the powders revealed that the structure of BaSrSiO4 is orthorhombic. The photoluminescence of the obtained phosphors were studied. The conversion ratios of the BaSrSiO4 starting materials are calculated from the weight loss. The CIE co-ordinates for the Eu doped BaSrSiO4 phosphors were x=0.30 and y=0.31. From the CIE chromaticity diagram for the emissions of Eu doped BaSrSiO4. This phosphor having color tenability and this phosphor has an important candidate of the lighting system.
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