{"title":"甲基环己烷在改性沸石上的氧化脱氢反应","authors":"A. I. Kerimov","doi":"10.54787/ccc-2710-4389-2020-00007","DOIUrl":null,"url":null,"abstract":"In the temperature range 280-390°C, at different ratios of methylcyclohexane:oxygen:nitrogen, space velocity of the gas mixture 1000-3000 h-1 and at atmospheric pressure it has been investigated the catalytic properties of synthetic and natural zeolites modified with various cations of transition and non-transition elements in the vapor-phase reaction of oxidative dehydrogenation of methylcyclohexane to methylcyclohexadiene-1,3. It has been found that the natural clinoptilolite with a combination of cations Co2+; Cr3+ in amounts of 0,5; and 0,25% wt., respectively, is an active catalyst for the oxidative dehydrogenation of methylcyclohexane to metylcyclohexadiene-1,3.","PeriodicalId":349868,"journal":{"name":"Caspian Corrosion Control Journal","volume":"30 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"OXIDATIVE DEHYDROGENATION OF METHYLCYCLOHEXANE OVER MODIFIED ZEOLITES\",\"authors\":\"A. I. Kerimov\",\"doi\":\"10.54787/ccc-2710-4389-2020-00007\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In the temperature range 280-390°C, at different ratios of methylcyclohexane:oxygen:nitrogen, space velocity of the gas mixture 1000-3000 h-1 and at atmospheric pressure it has been investigated the catalytic properties of synthetic and natural zeolites modified with various cations of transition and non-transition elements in the vapor-phase reaction of oxidative dehydrogenation of methylcyclohexane to methylcyclohexadiene-1,3. It has been found that the natural clinoptilolite with a combination of cations Co2+; Cr3+ in amounts of 0,5; and 0,25% wt., respectively, is an active catalyst for the oxidative dehydrogenation of methylcyclohexane to metylcyclohexadiene-1,3.\",\"PeriodicalId\":349868,\"journal\":{\"name\":\"Caspian Corrosion Control Journal\",\"volume\":\"30 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Caspian Corrosion Control Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.54787/ccc-2710-4389-2020-00007\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Caspian Corrosion Control Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.54787/ccc-2710-4389-2020-00007","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
OXIDATIVE DEHYDROGENATION OF METHYLCYCLOHEXANE OVER MODIFIED ZEOLITES
In the temperature range 280-390°C, at different ratios of methylcyclohexane:oxygen:nitrogen, space velocity of the gas mixture 1000-3000 h-1 and at atmospheric pressure it has been investigated the catalytic properties of synthetic and natural zeolites modified with various cations of transition and non-transition elements in the vapor-phase reaction of oxidative dehydrogenation of methylcyclohexane to methylcyclohexadiene-1,3. It has been found that the natural clinoptilolite with a combination of cations Co2+; Cr3+ in amounts of 0,5; and 0,25% wt., respectively, is an active catalyst for the oxidative dehydrogenation of methylcyclohexane to metylcyclohexadiene-1,3.
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