基于回归算法和Spearman秩相关系数的乙醇偶联反应研究

Shuya Peng, R. Cheng, Ziheng Dai
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引用次数: 0

摘要

C4烯烃用途广泛。乙醇是制备C4烯烃的清洁能源。研究乙醇法制备C4烯烃具有重要的现实意义。但在目前的C4烯烃制备工艺中,不同的调控条件对乙醇转化率和C4烯烃选择性有不同的影响,影响了工业生产效率。本文采用最小二乘法和Spearman相关系数法,研究了不同初始条件和温度对乙醇制备C4烯烃的影响。对于乙醇转化率[1]、C4烯烃选择性与温度之间的关系,首先以温度为自变量,乙醇转化率和C4烯烃选择性为因变量,通过最小二乘拟合得到方程,然后结合温度、转化率和选择性的Spearman相关系数,发现转化率和选择性随着温度的升高而增加。结果表明,C4烯烃的产率随反应时间的延长而降低。然后,结合随机森林回归算法和Spearman相关系数分析组合和温度对乙醇转化率和C4烯烃选择性的影响。研究发现,温度对乙醇的转化率和C4烯烃的选择性有重要影响[2];通过后者,判断影响的方向。结果表明,温度的升高对反应有促进作用,乙醇浓度的升高对乙醇转化率和C4烯烃选择性有影响,但负载方式对两者均无影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study on Ethanol Coupling Reaction Based on Regression Algorithm and Spearman Rank Correlation Coefficient
C4 olefins are widely used. Ethanol is a clean energy for the preparation of C4 olefins. It is of great practical significance to study the preparation of C4 olefins by ethanol. However, different regulation conditions have different ethanol conversion and C4 olefin selectivity in the current C4 olefin preparation process, which affects the industrial production efficiency. In this paper, the effects of different initial conditions and temperatures on the preparation of C4 olefins from ethanol were studied by means of least square fitting and Spearman correlation coefficient. For the relationship between ethanol conversion[1], C4 olefin selectivity and temperature, firstly, taking temperature as independent variable and ethanol conversion and C4 olefin selectivity as dependent variable, the equation is obtained by least square fitting, and then combined with the Spearman correlation coefficient of temperature, conversion and selectivity, it is found that the conversion and selectivity increase with the increase of temperature. It was found that the yield of C4 olefins decreased with the increase of reaction time. Then, the effects of combination and temperature on ethanol conversion and C4 olefin selectivity were analyzed by combining random forest regression algorithm and Spearman correlation coefficient. It was found that temperature had an important effect on the conversion of ethanol and the selectivity of C4 olefins[2]; Through the latter, the direction of influence is judged. It is found that the increase of temperature promotes the reaction, and the increase of ethanol concentration will affect the ethanol conversion and C4 olefin selectivity, but the loading mode has no effect on both.
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