纤维增强渣基碱活化砂浆在酸性环境中的性能研究

P. Perumal, Tirthankar Paul, T. Luukkonen, J. Röning, P. Kinnunen, M. Illikainen
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引用次数: 2

摘要

. 研究了不同纤维(钢纤维、玻璃纤维和玄武岩纤维)对高炉渣基碱活化砂浆在酸性环境下抗腐蚀性能的影响。将碱活化矿渣砂浆在5%硫酸和乙酸溶液中暴露30天。对质量变化、抗压强度和微观组织变化进行了评价。在普通砂浆中,醋酸环境下的残余强度为70%,硫酸环境下的残余强度仅为20%。FTIR光谱显示基质的降解,说明碱活化砂浆在硫酸环境中比醋酸更脆弱,这是由于碱活化砂浆具有腐蚀性。脱钙和醋酸钙的形成也阻碍了醋酸攻击中损害的进一步发展。当砂浆在酸性环境中发生降解时,纤维通过将基质结合在一起来帮助改善砂浆的性能。与普通砂浆相比,钢纤维掺入砂浆在醋酸和硫酸中表现出19%和7%的最大强度保留,其次是玻璃纤维和玄武岩纤维。SEM图像清晰地显示了酸性环境下纤维的脱粘和基体的崩解,从而导致强度损失。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Performance of Fibre-Reinforced Slag-Based Alkali Activated Mortar in Acidic Environment
. The main aim of the work is to study the effect of different fibres (steel, glass and basalt) on resistance of blast furnace slag-based alkali-activated mortar in acidic environment. The alkali-activated slag mortars were exposed to 5% sulfuric and acetic acid solutions for 30 days. Mass change, compressive strength and microstructural changes were evaluated. In plain mortar, it was observed that 70% of the strength was retained in acetic acid environment whereas only 20% of residual strength remains in sulphuric acid environment. FTIR spectroscopy shows the degradation of the matrix, which implies the alkali-activated mortar was more vulnerable in sulphuric acid environment due to its aggressive nature compared to acetic acid. Decalcification and formation of calcium acetate also hinders the further progress of damage in acetic acid attack. Fibres helped in improving the performance of the mortar by holding the matrix together when the degradation occurred in acidic environment. Compared to plain mortar, incorporation of steel fibres exhibited a maximum strength retention of 19% in acetic acid and 7% in sulphuric acid, followed by glass and basalt fibres. SEM images clearly show the debonding of fibres and disintegration of matrix in acidic environment, which resulted in strength loss.
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