金属纳米粒子光学增强的实际限制

G. Sun, J. Khurgin
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摘要

我们发展了一个简单而严谨的理论,通过放置在金属纳米颗粒附近的分子来增强光学吸收和发射。两种增强效应都与纳米颗粒的大小密切相关。以嵌入氮化镓的银纳米球为例,我们表明只有那些最初在吸收和发射光能方面效率低下的量子点、原子或分子才能获得强增强。然后讨论增强的实际限制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Practical limits of optical enhancement by metal nanoparticles
We develop a simple yet rigorous theory of the enhancement of optical absorption and emission by molecules placed in the vicinity of metal nanoparticles. Both enhancement effects exhibit strong dependence on the nanoparticle size. Using the example of Ag nanospheres embedded in GaN, we show that strong enhancement can be obtained only for those quantum dots, atoms, or molecules that are originally inefficient in absorbing as well as in emitting optical energy. We then discuss practical limits of enhancement.
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