机械化学有机合成-绿色化学的有力工具

D. Margetić
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引用次数: 0

摘要

有机化学反应通常是通过在各种有机溶剂中加热反应物来促进的。在新兴的合成方法中,机械化学被认为是有希望通过在固体状态下进行化学反应来减少对环境的影响。促进转化所需的能量通常是通过振动球磨获得的机械力。与传统的热溶液条件相比,机械化学的绿色方面在于减少溶剂的使用,缩短反应时间,室温和更好的反应收率。这篇小型评论给出了生态可持续机械化学有机反应的选定例子。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mechanochemical Organic Synthesis - Powerful Tool in Greener Chemistry
Organic chemical reactions are usually promoted by heating of reactants in various organic solvents. Amongst emerging synthetic methods mechanochemistry is recognized as being promissing in the reduction of the environmental impact by conducting chemical reactions in solid state. Energy required to promote transformation is obtained by mechanical force commonly by vibrational ball milling. Greener aspects of the mechanochemistry are in the reduction of solvent use, shorter reaction times, room temperature and better reactions yields in comparison to classical thermal solution conditions. This mini-review gives selected examples of eco-sustainable mechanochemical organic reactions.
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