亚甲基蓝和香蕉皮作为氧化还原液流电池RFB组分的研究

Moch Hanif Baktiyar, Anggita Adiningrum, Fatin Septianingsih, B. Poerwadi
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引用次数: 0

摘要

RFB(氧化还原液流电池)是一种二次电池,通过2对电子和质子的交替氧化还原反应提供化学和电力之间的能量转换。含钒活性成分的RFB (VRB)是一种应用广泛的RFB,但存在价格昂贵、有毒、溶剂(H2SO4)腐蚀性强等问题。因此,一种廉价且环保的有机电解质成分出现了,即亚甲基蓝和香蕉皮。亚甲基蓝具有2对电子-质子对,可提供可逆的氧化还原反应,具有作为RFB电解质活性成分的潜力。香蕉皮具有作为电解质溶剂的潜力,因为它们含有碳水化合物、柠檬酸和矿物质电解质(钾、钠盐、磷和镁),这些都支持香蕉皮的电解质特性。介绍了香蕉皮液发酵制电解质、加入亚甲基蓝及测试(恒流和应力)的阶段。测试结果表明,亚甲基蓝能够在RFB和香蕉皮上提供最佳性能(效率),因为电池中的电解质能够产生超过VRB输出电压的电压。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Utilization of Methylene Blue and Banana Peels as RFB Components (Redox Flow Battery)
RFB (Redox Flow Battery) is a secondary battery that provides energy conversion between chemistry and electricity through an alternating redox reaction by 2 pairs of electrons and protons. RFB with active ingredient Vanadium (VRB) is a type of RFB that is widely used and has problems such as the price of Vanadium is expensive, is toxic and the solvent (H2SO4) is corrosive. Therefore, an inexpensive and environmentally friendly organic electrolyte component emerged, namely Methylene Blue and banana peels. Methylene Blue has 2 electron-proton pairs which provide a reversible redox reaction and have the potential as an active ingredient in the RFB electrolyte. Banana peels have potential as an electrolyte solvent because they contain carbohydrates, citric acid and mineral electrolytes (potassium, sodium salt, phosphorus and magnesium) which support the electrolyte properties of banana peels. The stages of making electrolytes by fermentation of banana peel solution, addition of Methylene Blue and testing (galvanostatic and stress). The test results showed that Methylene Blue was able to provide the best performance (efficiency) on RFB and banana peels as an electrolyte in the battery was able to produce a voltage exceeding the VRB output voltage.
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