甲醛肟的红外傅立叶变换和二极管激光光谱

High Resolution Spectroscopy Pub Date : 1900-01-01 DOI:10.1364/hrs.1993.thb2

R. Bannai, G. Duxbury

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摘要

首先用Califano和l ttke1在气相中以低分辨率获得了最简单的肟CH2NOH的红外光谱。随后由Duxbury el .2和Duxbury3进行的高分辨率光谱分析表明，虽然最初的振动分析是正确的，但由低分辨率波段轮廓分析得出的过渡矩方向是错误的。

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Infrared Fourier Transform and Diode Laser Spectra of Formaldoxime

The infrared spectrum of the simplest oxime, CH2NOH, was first obtained at low resolution in the gas phase by Califano and Lüttke1. Subsequent high resolution spectroscopy by Duxbury el al.2 and by Duxbury3 demonstrated that although the original vibrational analysis was correct, the directions of the transition moments derived fro from the analysis of low resolution band contours were not.

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High Resolution Spectroscopy

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