基于金-多糖纳米复合材料的pH响应可调谐等离子体谐振器

S. Kravchenko, P. Boltovets, Oleksiy Kovalenko, B. Snopok
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引用次数: 0

摘要

结合高稳定性和可调活性的先进成分的发展是现代跨学科科学的前沿趋势。这一重要的科学问题是通过在天然多糖的自适应有机基质结构中嵌入等离子体纳米结构来解决的。这使得获得独特的材料成为可能,在合成阶段和使用时,由于外部光激发无机结构的等离子体共振,有可能针对特定任务进行优化。我们报告了基于触发因子(即pH)的复合材料的物理化学和结构特征的研究结果,这些触发因子的变化导致大分子的构象转变。将纳米复合材料视为分子纳米机器人,“…原子水平的自主预编程结构…”,为设计一种自适应的自然纳米机器开辟了道路,其特性可以受外部影响控制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
pH Responsive Tunable Plasmonic Resonators Based on Gold-Polysaccharide Nanocomposites
: The development of advanced compositions that combine high stability and tunable activity is a forefront trend in modern interdisciplinary science. This important scientific problem is solved by the formation of plasmonic nanostructures embedded in the structure of the adaptive organic matrix of natural polysaccharides. This makes it possible to obtain unique materials with the possibility of optimization for specific tasks both at the stage of synthesis and when used due to the excitation of plasmon resonance of inorganic architecture by external light. We report the results of the study of physicochemical and structural features of composites depending on trigger factors (i.e., pH), the change of which leads to conformational transformations of macromolecules. Consid-ering a nanocomposite as molecular nanobot, “…autonomic preprogrammed structure of atomic level…”, opens the way to design an adaptive natural nanomachine, the properties of which can be controlled by external influences.
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