{"title":"Hg | Hg2Cl2(s)， Cl-电极在二氧六烷-水介质中若干温度下的标准电极电位及相关热力学量","authors":"Mustafa B. Shamsuddin, Anil Kumar Chaohadia","doi":"10.32628/ijsrch23823","DOIUrl":null,"url":null,"abstract":"From e.m.f measurements of cells (C-1) and (C-2) it has been established that modified Davies equation is valid in dioxane-water media at least upto 30% dioxane by weight. E0m values of Hg | Hg2Cl2(s), Cl- electrode in dioxane-water media having 10, 20 and 30% dioxane by weight and the corresponding thermodynamic parameters have been determined at 288.15, 298.15, 308.15 and 318.15 0K.\n\n(Pt),H2 ( l atm ) | HCl(m1) x% Dioxane (100-x)% H2O, Hg2Cl2(s) | Hg … (C-1)\n\n(Pt),H2 ( l atm ) | HCl(m1) BaCl2(m2)x% Dioxane (100-x)% H2O, Hg2Cl2(s) | Hg … (C-2)","PeriodicalId":430334,"journal":{"name":"International Journal of Scientific Research in Chemistry","volume":"12 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Standard Electrode Potential of Hg | Hg2Cl2(s), Cl- Electrode in Dioxane-Water Media at a Number of Temperature and the Related Thermodynamic Quantities\",\"authors\":\"Mustafa B. Shamsuddin, Anil Kumar Chaohadia\",\"doi\":\"10.32628/ijsrch23823\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"From e.m.f measurements of cells (C-1) and (C-2) it has been established that modified Davies equation is valid in dioxane-water media at least upto 30% dioxane by weight. E0m values of Hg | Hg2Cl2(s), Cl- electrode in dioxane-water media having 10, 20 and 30% dioxane by weight and the corresponding thermodynamic parameters have been determined at 288.15, 298.15, 308.15 and 318.15 0K.\\n\\n(Pt),H2 ( l atm ) | HCl(m1) x% Dioxane (100-x)% H2O, Hg2Cl2(s) | Hg … (C-1)\\n\\n(Pt),H2 ( l atm ) | HCl(m1) BaCl2(m2)x% Dioxane (100-x)% H2O, Hg2Cl2(s) | Hg … (C-2)\",\"PeriodicalId\":430334,\"journal\":{\"name\":\"International Journal of Scientific Research in Chemistry\",\"volume\":\"12 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-04-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Scientific Research in Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.32628/ijsrch23823\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Scientific Research in Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.32628/ijsrch23823","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Standard Electrode Potential of Hg | Hg2Cl2(s), Cl- Electrode in Dioxane-Water Media at a Number of Temperature and the Related Thermodynamic Quantities
From e.m.f measurements of cells (C-1) and (C-2) it has been established that modified Davies equation is valid in dioxane-water media at least upto 30% dioxane by weight. E0m values of Hg | Hg2Cl2(s), Cl- electrode in dioxane-water media having 10, 20 and 30% dioxane by weight and the corresponding thermodynamic parameters have been determined at 288.15, 298.15, 308.15 and 318.15 0K.
(Pt),H2 ( l atm ) | HCl(m1) x% Dioxane (100-x)% H2O, Hg2Cl2(s) | Hg … (C-1)
(Pt),H2 ( l atm ) | HCl(m1) BaCl2(m2)x% Dioxane (100-x)% H2O, Hg2Cl2(s) | Hg … (C-2)
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