A. Grupp, Oliver Haufe, M. Jansen, M. Mehring, M. Panthöfer, J. Rahmer, A. Reich, M. Rieger, X. Wei
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引用次数: 4
摘要
新型碱土内嵌富勒烯M@Cn (M = Ca, Sr;n = 74,76)，通过高效液相色谱分离，并通过质量、拉曼、VIS - NIR和光激发三重态ESR光谱进行了表征。实验结果与量子化学研究结果进行了比较。
Synthesis, Isolation and Characterisation of New Alkaline Earth Endohedral Fullerenes M@Cn (M = Ca, Sr; n = 74, 76)
New alkaline earth endohedral Fullerenes M@Cn (M = Ca, Sr; n = 74, 76), prepared by means of the RF‐method, have been isolated by HPLC and characterised by means of mass, Raman, VIS‐NIR and photo‐excited triplet‐state ESR spectroscopy. The experimental findings are compared with the results of quantum‐chemical investigations.
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