催化反应中类水滑石材料的拉曼光谱表征

Luciano Honorato Chagas, Sandra Shirley Ximeno Chiaro, Alexandre Amaral Leitão, R. Diniz
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引用次数: 0

摘要

本章简要介绍了水滑石的定义、结构特征和主要应用。水滑石是一种有趣的多功能材料,在许多领域都有广泛的应用。特别地,一些使用水滑石或由这些材料衍生的混合氧化物的催化反应被处理(乙醇蒸汽重整,光化学转化,加氢脱硫)。利用拉曼光谱和其他技术,如粉末x射线衍射(XRD),扩展x射线吸收精细结构(EXAFS),氢的温度程序还原(H2-TPR),傅里叶变换红外(FTIR)和密度泛函数理论(DFT)模拟,通过当前文献中描述的例子来描述这种类型的材料。从这个意义上说,必须进行多学科的努力,以增加对这些材料的性质和在大多数不同反应中的催化行为的理解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Raman Spectroscopy for Characterization of Hydrotalcite-like Materials Used in Catalytic Reactions
This chapter covers a brief review of the definition, structural characteristics and main applications of hydrotalcite, an interesting multifunctional material which finds applicability in different areas. Particularly, some catalytic reactions using hydrotalcite or mixed oxides derived from these materials are addressed (Ethanol Steam Reforming, Photochemical conversions, Hydrodesulfurization). The use of Raman Spectroscopy associated with other techniques, such as powder X-ray diffraction (XRD), Extended X-ray Absorption Fine-Structure (EXAFS), Temperature Programmed Reduction of hydrogen (H2-TPR), Fourier-Transform Infrared (FTIR) and Density Functional Theory (DFT) simulations, to characterize this type of material is addressed through examples described in the current literature. In this sense, multidisciplinary efforts must be made in order to increase the understanding of the properties of these materials and the catalytic behavior in the most varied reactions.
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