薄膜碲化镉太阳能电池I-V特性的交叉建模

M. Burgelman, P. Nollet, S. Degrave, J. Beier
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引用次数: 11

摘要

高效CdTe薄膜太阳能电池的I-V曲线显示在正向区域有一个扭结(翻转),这一事实得到了很好的研究,并归因于接触势垒,例如在CdTe层的后接触处。此外,由于在照明下接触饱和电流的增加,亮和暗的I-V特性相交(交叉)。我们在许多场合观察到,当一些参数发生变化时,如照明强度或处理条件的最小变化,几个I-V曲线的风扇都在第一象限的一个单点相交(正向电流和电压)。我们将此归因于CdTe背接触肖特基势垒处电子少数电流的贡献。我们将展示这如何解释单点相交。通过理论分析、数值模拟和实验对假设的有效性进行了讨论。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Modeling the cross-over of the I-V characteristics of thin film CdTe solar cells
The I-V curves of high efficiency CdTe thin film solar cells show a kink in the forward region (roll-over) this fact is well studied and ascribed to a contact barrier e.g. at the back contact of the CdTe layer. Also, light and dark I-V characteristics intersect (cross-over), due to an increase of the contact saturation current under illumination. We observed on many occasions that a fan of several I-V curves all intersect at one single point in the first quadrant (forward current and voltage), when some parameter is varied, like illumination intensity or minimal changes of processing conditions. We ascribe this to the contribution of electron minority current at the CdTe back contact Schottky barrier. We show how this can explain the one-point-intersection. The validity of the assumptions are discussed with theoretical considerations, numerical simulations and experiments.
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