再生聚对苯二甲酸乙酯/再生聚丙烯共混物:湿热处理的效果

S. Aminuddin, L. Wei, H. Hamada, N. Adnan
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引用次数: 3

摘要

消费后的聚对苯二甲酸乙二醇酯(PET)和聚丙烯(PP)产生的废物量,特别是在包装工业中,刺激了对再生PET和再生PP生产创新产品的深入研究,用于复合材料和合成纤维工业。虽然PP由于其化学结构中没有极性基团而吸收很少的水分,但主要关注的是吸湿性PET在存在水时的稳定性。本研究将添加增容剂的再生聚(对苯二甲酸乙酯)/再生聚丙烯(RPET/RPP)共混物注射到哑铃样品中,然后在60°C的水浴中进行湿热老化,以确定吸湿量。在吸水量增加期间的机械性能评估提供了材料在暴露于水和温度后的耐久性信息。增容剂含量越高,吸水率越高,拉伸强度明显下降。这表明相容剂主要存在于RPET和RPP相之间的界面,形成一个对湿热都敏感的相间区。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Recycled poly(ethylene terephthalate)/recycled polypropylene blend: Effect of hygrothermal treatment
The amount of waste that arise from post-consumer poly(ethylene terephthalate) (PET) and polypropylene (PP) especially in the packaging industry have stimulated an in depth investigation to produce innovative new products from recycled PET and recycled PP for application in the composite and synthetic fiber industries. Although PP absorbs very little moisture due to the absence of polar groups in its chemical structure, the main concern is the stability of hygroscopic PET in the presence of water. In this work, recycled poly(ethylene terephthalate)/ recycled polypropylene (RPET/RPP) blends with addition of compatibilizer was injection molded into dumbbell specimens and then subjected to hygrothermal aging in a water bath set at 60°C to determine the amount of moisture absorption. Evaluation of mechanical performance during the increment of water uptake provides information on the durability of the material after exposure to both water and temperature. Water absorption rate was found to be higher when higher compatibilizer content was present resulting into a significant decline in tensile strength. This suggests that the compatibilizers are mostly present at the interface between RPET and RPP phases to form an interphase region that is sensitive to both moisture and heat.
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