高效单掺杂白光磷光二极管

Q. Niu, Yunhua Xu, Junbiao Peng, Yong Zhang
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引用次数: 0

摘要

用掺杂红色磷光染料的蓝绿色荧光聚合物单层发射层制备了高效聚合物白光二极管。器件结构由ITO/聚(乙烯二氧噻吩):聚(苯乙烯磺酸)(PEDOT:PSS)/聚(n -乙烯基咔唑)(PVK) /聚(9,9-二辛基芴)(PFO): Ir-配合物(Ir(DMFPQ)2pbm) /CsF/Al组成。PFO向Ir(DMFPQ)2pbm发生能量转移,导致PFO电致发光猝灭。将PFO:Ir(DMFPQ)的重量比调整为2pbm至99.7:0.3,实现了纯净高效的白光发射。wled在7.8V时的最大电流效率为9.6cd/A,在11.4V时的最大亮度为13491cd/m2。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
High efficiency single-doped white phosphorescent light-emitting diodes
Efficient polymer white-light-emitting diodes (WPLEDs) have been fabricated with a single emissive layer, blue-green fluorescence polymer doped with a red phosphorescent dye. The device structure consists of ITO/poly(ehtlenedioxythiophene):poly(styrene sulfonic acid) (PEDOT:PSS)/poly(N-vinylcarbazole) (PVK) /poly(9,9-dioctylfluorene) (PFO): Ir-complex (Ir(DMFPQ)2pbm) /CsF/Al. Energy transfer occurred from PFO to Ir(DMFPQ)2pbm, leading to electroluminescence quench of PFO. Pure and efficient white light emission was realized by tuning the weight ratio of PFO:Ir(DMFPQ)2pbm to 99.7: 0.3. The maximum current efficiency and luminance of WPLEDs were 9.6cd/A at 7.8V and 13491cd/m2 at 11.4V, respectively.
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