独立聚合物电解质膜(PEM)燃料电池堆的简化动态仿真模型(原型)

D. Ali
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引用次数: 25

摘要

由于对电能的需求不断增加,加上最近油价不稳定导致电价上涨,加上现有能源转换装置排放的废气导致空气质量下降,因此加强了对替代可再生电能的研究。本文建立了一个动态电化学模型来模拟聚合物电解质膜燃料电池(PEMFC)系统,以便利用这一有前途的新技术开发和改进发电系统。虽然也有其他的模型被生产出来,但大多数模型都是通过估计特定操作条件下的电压来捕捉燃料电池(FC)的稳态行为。所提出的模型考虑了负载电流、输入反应物气体压力、燃料电池工作温度以及燃料电池体内的质量/传热瞬态特征等不同动态条件的影响。它预测暂态动力学的能力也将证明在试图制定控制策略时是有用的。提出的模型强度是模块化燃料电池的基本热物理行为,并开发一个模块化块,可以用作燃料电池研究所需的任何其他原理图解决方案的一部分。开发的模块化模块(原型)展示了大多数基本的燃料电池特性,并结合了在其运行过程中发生的基本物理和电化学过程,允许其轻松调节具有不同电池参数的其他燃料电池的建模,并允许在任何操作或设计配置下调查其行为。该原型在将来研究将燃料电池集成到配电系统中是有用的。提出的模块化模块在SIMULINK中实现,并通过生成模型结果并将其与Ballard NEXAtrade Power模块的基准结果进行比较来验证。并与另一种简化模型进行了比较;两种模型的样本结果表明,所开发的模型在模拟燃料电池时更加准确,特别是在高工作电流密度下。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A simplified dynamic simulation model (prototype) for a stand-alone Polymer Electrolyte Membrane (PEM) fuel cell stack
The ever increasing demand for electrical energy and the rise in the electricity prices due to the recent instability of the oil prices in addition to the degrading of the air quality resulting from the emissions of the existing energy conversion devices has intensified research into alternative renewable sources of electrical energy. In this paper a dynamic electrochemical model is developed to simulate a polymer electrolyte membrane fuel cell (PEMFC) system to allow the development and improvement of electrical energy generation systems using this new promising technology. Although other models have been produced but most of these capture the fuel cell (FC) steady state behaviour by estimating its voltage for a particular set of operating conditions. The proposed model allows the incorporation of effects of different dynamic conditions in load current, pressure of input reactant gases, fuel cell operating temperature as well as the mass/heat transfer transient features in the fuel cell body. Its capability of predicting transient dynamics will also prove useful when attempting to develop a control strategy. The proposed model strength is modularizing the fundamental thermal- physical behaviour of a fuel cell and developing a modular block that can be used as a part of any other schematic solution required for fuel cells' study. The developed modular block (prototype) exhibits most of the basic fuel cell properties and incorporates essential physical and electrochemical processes that happen along its operation, allowing its' easy moderation for modelling other fuel cells with different cell parameters and allow investigation of their behaviour for any operating or design configuration. The prototype can be useful in future in studying the integration of fuel cells into distribution power systems. The proposed modular block is implemented in SIMULINK and is verified by generating model results and comparing this to benchmark results for a Ballard NEXAtrade Power module. The proposed model was also compared to another simplified model; sample results for a Ballard V PEMFC were generated for both models indicating that the developed model is more accurate in simulating the fuel cell especially at high operating current densities.
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