天然橡胶和合成橡胶在实际结构中随温度变化的机械性能

Samiul Kaiser, R. Rabbani, Reaz Ahmed, S. Kaiser
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引用次数: 1

摘要

本文研究了天然橡胶和合成橡胶在不同温度下的力学性能,包括真实热处理和老化热处理。为此,轮胎橡胶和轴承垫橡胶分别被认为是天然橡胶和合成橡胶中最受管制的橡胶。实验结果证实,实际温度对橡胶力学性能的影响大于老化温度,因为环境温度加剧了橡胶的热运动,改变了橡胶的分子排列,而不是老化样品在微风作用下恢复了力学性能。除硬度外,轴瓦橡胶在抗拉强度、伸长率、杨氏模量、泊松比等力学性能方面均优于轮胎橡胶。在老化处理条件下,由于天然橡胶的分子结构具有极有序的长链结构,其退化的力学性能得到了很好的恢复。两种橡胶显微照片上的显著差异表明,由于其高度控制的分子排列,轮胎橡胶由均匀的颗粒组成。热处理后,随着温度的升高,微观组织变得粗糙,孔洞尺寸变大,二次交联反应引发裂纹。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Temperature Dependent Mechanical Properties of Natural and Synthetic Rubber in Practical Structures
In this proposal the mechanical properties of natural and synthetic rubbers are studied under different temperatures both real and ageing heat treatment conditions. For this purpose, tire rubber and bearing pad rubber are considered as they are most governed in natural and synthetic rubber respectively. The experimental results confirm that the impact of real temperature is higher on the mechanical properties than that of ageing temperature because of ambient temperature aggravate thermal motion and changes the molecular arrangement of rubber other than the ageing samples recovers the mechanical properties during breezy. Except hardness, all the cases in terms of mechanical properties like tensile strength, elongation, Young’s modulus and Poisson’s ratio of bearing pad rubber provide the higher performance than the tire rubber. Under ageing treatment condition the degraded mechanical properties recover well by the natural rubber since extremely ordered long chain of the molecular structure. The significant differences in the micrographs of the two rubbers suggest that tire rubber consists of uniform grains because of its highly controlled molecular arrangement. Under heat treatment the microstructure turned rougher and the size of the voids became larger as temperature increases the secondary cross linking reaction which initiate to cracks.
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