基于蛋白石基质的三维纳米复合材料的磁共振和反共振

A. Rinkevich, D. V. Perov, M. Samoylovich, S. М. Klescheva, E. Kuznetsov
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引用次数: 0

摘要

近年来,人们对蛋白石基质的红外和微波特性进行了深入的研究。有人认为,在球间空隙中含有磁性材料纳米颗粒的蛋白石基质可能成为最有前途的一类用于厘米和毫米波器件的材料[2,3]。镍锌、钴锌和其他铁氧体似乎是合适的填充材料,因为它们具有高电阻率、低介电损耗、高居里温度和化学稳定性等特性。微波方法的应用似乎是有效的,因为这些方法可以估计材料的动力学和弛豫参数。本文讨论了含不同铁素体尖晶石纳米颗粒的蛋白石基质在球间空隙中的微波特性。微波特性是在毫米波波段的频率上测量的。通过磁性纳米复合材料的微波信号的变化主要是由于磁共振条件下表面阻抗的变化和波的吸收。在较高的频率下,反共振在低于共振场的场中是可能的。反共振表现为透射系数和/或反射系数的最大值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Magnetic resonance and antiresonance in 3D nanocomposites based on opal matrices
In recent years, the infrared and microwave properties of opal matrices have been intensively studied [1]. It is thought that the opal matrices containing nanoparticles of magnetic materials in the intersphere voids may form a most promising class of materials used in centimeter- and millimeter-wave devices [2, 3]. Nickel-zinc, cobalt-zinc, and other ferrites seem to be proper materials for the filling owing to a lucky combination of such properties as high resistivity, low dielectric loss, high Curie temperature, and chemical stability. Application of microwave methods seems to be effective since these methods enables to estimate the dynamical and relaxation parameters of materials. Microwave properties of opal matrices containing the nanoparticles of different ferrite-spinels in the inter-sphere voids are discussed in this work. Microwave properties are measured at frequencies of millimeter waveband. Variations of a microwave signal passed through the magnetic nanocomposite occur mainly due to variations of the surface impedance under magnetic resonance condition and due to absorption of the wave. At higher frequencies the antiresonance is possible in fields lower than the resonance field. The antiresonance manifests itself as a maximum of transmission and/or reflection coefficients.
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