回收瓶级涤纶长丝的拉伸性能试验研究

A. M
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引用次数: 1

摘要

本研究比较了再生瓶级PET (R-PET)和新瓶级PET (BG-PET)连续纱线(长丝)的拉伸性能。以原纤维级PET (FG-PET)为对照。纺丝机和拉丝机是分开进行的。抽取比分别为2.8、3.0、3.2和3.55。结果表明,拉伸率越高,样品的密度和结晶度越高。在FG样品的情况下,这种增加更大,特别是在较高的拉伸比下。这表明再生聚合物在拉伸过程中的结晶能力比新聚合物弱。在较高的拉伸比下生产的纱线具有较高的初始模量,这是由其结晶度的增加所证实的。R-PET和BG-PET样品的表观晶体尺寸高于FG-PET样品,这与它们的初始模量变化是一致的。在拉伸比为3.2时,R-PET转化为全拉伸纱(FDY)。在此拉伸比下,R-PET的韧性(3.18g/den)比FG-PET的韧性(2.83g/den)高11%。拉伸后的R-PET长丝与拉伸后的FG-PET丝相比,具有较好的性能。这可能与R-PET纱具有较高的特性粘度和双折射有关。由于拉伸比的增加,在所有样品中长丝的抗拉强度和初始模量都有相当大的提高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Experimental Study on Draw-Ability of Filament Yarns Produced from Recycled and Bottle Grade PET
In this study, draw-ability of continuous yarns (filament) from recycled bottle grade PET (R-PET) and new bottle grade PET (BG-PET) were compared. Virgin fiber grade PET (FG-PET) was used as the control. Spinning and draw machine were performed separately in this study. The draw ratios were 2.8, 3.0, 3.2, and 3.55. It was found that higher draw ratios result in higher density and crystallinity for all samples. This increase was larger in the case of FG samples, especially at higher draw ratios. This suggests that crystallization ability in the drawing process for the recycled polymer is weaker than the new polymer. Higher initial modulus of yarns produced at higher draw ratios is confirmed by the increase in their crystallinity values. Higher values of apparent crystal size of R-PET and BG-PET samples than those of FG-PET samples are in accordance to their initial modulus changes. In the draw ratio of 3.2, R-PET converted to Fully Drawn Yarn (FDY). In this draw ratio, tenacity of R-PET (3.18g/den) showed 11% higher value compared to that of FG-PET (2.83g/den). The drawn R-PET filament yarn presented desirable properties compared to the drawn FG-PET yarn. This might be attributed to the higher intrinsic viscosity and birefringence of the R-PET yarn. As a result of an increase in draw ratio, there is an advanced considerable increase in the tensile strengths and initial modulus of filaments in all samples..
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