玄武岩微纳纤维填充量为15-80%(重量比)的环氧聚合物复合材料的强度、耐热性、耐化学性的测定

D. Rassokhin, D. Starokadomsky, A. Ishchenko, O. Tkachenko, M. Reshetnyk, Lyudmyla Kоkhtych
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引用次数: 6

摘要

实验证明了制备含微量玄武岩纤维(MNBF) 15 - 80%的复合材料的可能性;它的特点是一系列性能的改进,如强度、耐化学性和防火性。研究表明,在平均浓度(高达15%)下,复合材料的性能与未填充的聚合物(n -聚合物)略有不同。然而,在重量比为50%,特别是重量比为80%时,通过扫描电镜证实,性能发生了严重变化,表现为形貌的深刻变化。已经确定,微玄武岩的引入可以将压缩强度提高到10%(测量误差小于5%),并且只有在非常高的填充量为重量的80%时才可以。微玄武岩的强化作用表现为复合材料在水中的压缩载荷增加,其弹性模量可达6 - 12%。已经确定,填充后弯曲强度下降(约2倍)是一种趋势,几乎所有环氧填料的特征。玄武岩纤维也不例外。只有那些带有玄武岩粗纱的样品自然例外,这增加了它们的弯曲强度。与此同时,高含量(但不是重量的15%)表明,弯曲时模组的增长几乎是两倍:对于粗纱复合材料来说,这是非常重要的,从实用的角度来看。微玄武岩充填降低了35%的膨胀率和程度Н 2 О 2 -越活跃,充填率越高。从视觉上看,它们表现出过氧化氧化的迹象(白色);然而,没有发现明显的破坏(如在丙酮中)。我们已经建立了曲线来估计聚合物的膨胀程度。此外,还研究了填充率为50%和80%的高填充复合材料的膨胀特性。研究结果表明,复合材料结构的压实程度和对侵蚀环境的抵抗能力是通过增加无机相的份额来提高的
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Determining the Strength and Thermal, Chemical Resistance of the Epoxy Polymer Composite Filled With Basalt Micro Nano Fiber in the Amount of 15–80% by Weight
The possibility to obtain composites containing the micronano basalt fiber (MNBF) in the amount of 15‒80 % by weight has been experimentally demonstrated; it is distinguished by a series of improved properties such as strength, chemical and fire resistance. It has been shown that at average concentrations (up to 15 %) the properties of the composite differ slightly from the unfilled polymer (N-polymer). However, at 50 % by weight, and especially 80 % by weight, there are serious changes in the properties manifested by a profound change in the morphology, as confirmed by SEM-microscopy. It has been established that the introduction of microbasalt could increase strength at compression to 10 % (with a measurement error less than 5 %), and only at a very high filling in the amount of 80 % by weight. Strengthening the effect of microbasalt is expressed in an increase in the compression load of a composite aged in water and its elastic modulus up to 6–12 %. It has been determined that the drop in bending strength (by about 2 times) after filling is a tendency that is characteristic of almost all epoxy fillers. Basalt fiber was no exception. The natural exception is only those samples with basalt roving, which increase their strength at bending. At the same time, the high content (but not at 15 % by weight) has revealed an almost two-fold growth in the module at bending: higher for the composite with roving, which is very important from a practical point of view. Microbasalt filling reduces the rate and degree of swelling in 35 % Н 2 О 2 ‒ the more active the higher the percentage of filling. Visually, they demonstrate the signs of oxidation with peroxide (white); however, no significant destruction (as in acetone) has been detected. We have built the curves to estimate the degree of the polymer swelling. In addition, the swelling character of the composites with a high degree of filling, in the amount of 50 and 80 % by weight, has been investigated. The study results led to the conclusion of the degree of compaction of the structure of the composite and the increase in its resistance to aggressive environments through an increase in the share of the inorganic phase
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