Jiachen Zhang, Tai-wen Huang, Fan Lu, Kaili Cao, Dong Wang, J. Zhang, Jun Zhang, H. Su, Lin Liu
{"title":"揭示ni基高温合金中γ/γ′界面处的Re偏析","authors":"Jiachen Zhang, Tai-wen Huang, Fan Lu, Kaili Cao, Dong Wang, J. Zhang, Jun Zhang, H. Su, Lin Liu","doi":"10.2139/ssrn.3813384","DOIUrl":null,"url":null,"abstract":"The distribution of Rhenium (Re) in a Ni-based single crystal superalloy is characterized and specified by atom probe tomography (APT) after different heat treatment (including long-term aging). At high temperatures (950-1100°C), the actual effective diffusion providing γ΄ coarsening is becoming much bigger than Re diffusion in γ matrix, consequently Re atoms are insufficient to diffuse away and keep accumulating, leading to forming segregation at γ/γ′ interface. While at low temperatures (800-900°C), the Re diffusion is capable to balance the effective diffusion for γ΄ coarsening. After introducing more alloys with different Re content and different aging temperatures, Re segregation is irrelevant to the Re content but highly temperature-dependent. These results provide a novel perspective on the comprehension of the Re effect on the γ΄ coarsening in Ni-based superalloy and will be valuable to both improving the γ/γ′ microstructure stability and designing high-performance superalloys.","PeriodicalId":159806,"journal":{"name":"ChemRN: Metals & Alloys (Topic)","volume":"109 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2021-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"12","resultStr":"{\"title\":\"Unveiling the Re segregation at γ/γ′ interface in Ni-based Superalloy\",\"authors\":\"Jiachen Zhang, Tai-wen Huang, Fan Lu, Kaili Cao, Dong Wang, J. Zhang, Jun Zhang, H. Su, Lin Liu\",\"doi\":\"10.2139/ssrn.3813384\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The distribution of Rhenium (Re) in a Ni-based single crystal superalloy is characterized and specified by atom probe tomography (APT) after different heat treatment (including long-term aging). At high temperatures (950-1100°C), the actual effective diffusion providing γ΄ coarsening is becoming much bigger than Re diffusion in γ matrix, consequently Re atoms are insufficient to diffuse away and keep accumulating, leading to forming segregation at γ/γ′ interface. While at low temperatures (800-900°C), the Re diffusion is capable to balance the effective diffusion for γ΄ coarsening. After introducing more alloys with different Re content and different aging temperatures, Re segregation is irrelevant to the Re content but highly temperature-dependent. These results provide a novel perspective on the comprehension of the Re effect on the γ΄ coarsening in Ni-based superalloy and will be valuable to both improving the γ/γ′ microstructure stability and designing high-performance superalloys.\",\"PeriodicalId\":159806,\"journal\":{\"name\":\"ChemRN: Metals & Alloys (Topic)\",\"volume\":\"109 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-03-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"12\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemRN: Metals & Alloys (Topic)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2139/ssrn.3813384\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemRN: Metals & Alloys (Topic)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2139/ssrn.3813384","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Unveiling the Re segregation at γ/γ′ interface in Ni-based Superalloy
The distribution of Rhenium (Re) in a Ni-based single crystal superalloy is characterized and specified by atom probe tomography (APT) after different heat treatment (including long-term aging). At high temperatures (950-1100°C), the actual effective diffusion providing γ΄ coarsening is becoming much bigger than Re diffusion in γ matrix, consequently Re atoms are insufficient to diffuse away and keep accumulating, leading to forming segregation at γ/γ′ interface. While at low temperatures (800-900°C), the Re diffusion is capable to balance the effective diffusion for γ΄ coarsening. After introducing more alloys with different Re content and different aging temperatures, Re segregation is irrelevant to the Re content but highly temperature-dependent. These results provide a novel perspective on the comprehension of the Re effect on the γ΄ coarsening in Ni-based superalloy and will be valuable to both improving the γ/γ′ microstructure stability and designing high-performance superalloys.