Electrical Conductivity of Molten Salts and Ionic Conduction in Electrolyte Solutions

A microscopic description for the partial DC conductivities in molten salts has been discussed by using a Langevin equation for the constituent ions. The memory function γ (t) can be written as in the form of a decaying function with time. In order to solve the mutual relation between the combined-velocity correlation functions Z σ (cid:1) (t) and the memory function γ (t) in a short time region, a new recursion method is proposed. Practical application is carried out for molten NaCl by using MD simulation. The fitted function is described by three kinds of Gaussian functions and their physical backgrounds are discussed. Also the electrical conductivity in aqueous solution of electrolyte has been obtained, based on a generalized Langevin equation for cation and anion in it. This treatment can connect and compare with the work of computer simulation. The obtained results for concentration dependence of electrical conductivity are given by a function of the square root of concentration. The electrophoretic effect and the relaxation one are also discussed.