S. Šorli, M. A. Tena, J. Badenes, M. Llusar, G. Monrós
{"title":"(Ni,M,Ti)O2 (M = Sb, Nb)黄色陶瓷颜料中镍前驱体的研究","authors":"S. Šorli, M. A. Tena, J. Badenes, M. Llusar, G. Monrós","doi":"10.1179/096797804225012710","DOIUrl":null,"url":null,"abstract":"Abstract NixTi1 - 3xM2xO2 (M = Sb, Nb; 0·05 ≤ x ≤ 0·10) samples have been synthesised from mixtures of NiO, Nb2O5, Sb2O3, and TiO2. From characterisation of these samples, x = 0·05 was chosen to compare results with different nickel precursors. Thus samples of Ni0·05Ti0·85M0·10O2 (M = Sb, Nb) were also prepared from NiCO3.3Ni(OH)2.4H2O, NiCl2.6H2O, Ni(NO3)2.6H2O, NiSO4.6H2O, and Ni(CH3COO)2.4H2O. A eutectic mixture of alkaline halides (NaF:2NaCl) was used as fluxing agent. Optimal yellow colour was found in the mixture of NiSO4.6H2O, Sb2O5, and TiO2 fired at 1100°C for 2 h.","PeriodicalId":350675,"journal":{"name":"British Ceramic Transactions","volume":"2 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2004-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"Study of nickel precursors in (Ni,M,Ti)O2 (M = Sb, Nb) yellow ceramic pigments\",\"authors\":\"S. Šorli, M. A. Tena, J. Badenes, M. Llusar, G. Monrós\",\"doi\":\"10.1179/096797804225012710\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract NixTi1 - 3xM2xO2 (M = Sb, Nb; 0·05 ≤ x ≤ 0·10) samples have been synthesised from mixtures of NiO, Nb2O5, Sb2O3, and TiO2. From characterisation of these samples, x = 0·05 was chosen to compare results with different nickel precursors. Thus samples of Ni0·05Ti0·85M0·10O2 (M = Sb, Nb) were also prepared from NiCO3.3Ni(OH)2.4H2O, NiCl2.6H2O, Ni(NO3)2.6H2O, NiSO4.6H2O, and Ni(CH3COO)2.4H2O. A eutectic mixture of alkaline halides (NaF:2NaCl) was used as fluxing agent. Optimal yellow colour was found in the mixture of NiSO4.6H2O, Sb2O5, and TiO2 fired at 1100°C for 2 h.\",\"PeriodicalId\":350675,\"journal\":{\"name\":\"British Ceramic Transactions\",\"volume\":\"2 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"British Ceramic Transactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1179/096797804225012710\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"British Ceramic Transactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1179/096797804225012710","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Study of nickel precursors in (Ni,M,Ti)O2 (M = Sb, Nb) yellow ceramic pigments
Abstract NixTi1 - 3xM2xO2 (M = Sb, Nb; 0·05 ≤ x ≤ 0·10) samples have been synthesised from mixtures of NiO, Nb2O5, Sb2O3, and TiO2. From characterisation of these samples, x = 0·05 was chosen to compare results with different nickel precursors. Thus samples of Ni0·05Ti0·85M0·10O2 (M = Sb, Nb) were also prepared from NiCO3.3Ni(OH)2.4H2O, NiCl2.6H2O, Ni(NO3)2.6H2O, NiSO4.6H2O, and Ni(CH3COO)2.4H2O. A eutectic mixture of alkaline halides (NaF:2NaCl) was used as fluxing agent. Optimal yellow colour was found in the mixture of NiSO4.6H2O, Sb2O5, and TiO2 fired at 1100°C for 2 h.
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