户外复合高分子材料老化试验

J. Aceves, I. D. Couper, M. A. Sanchez
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引用次数: 0

摘要

两种建议的技术,热分析和红外分光光度法被用来表征紫外线辐射对聚合物材料造成的变质过程。提出了光氧化机理。跟踪电阻的损耗与聚合物表面氧化的关系与老化时间成正比。新、旧样品的红外光谱与热分析结果吻合较好;因此,热吸收光谱和红外光谱数据是表征受紫外线辐射老化的聚合物材料的两种有用的工具。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Aging experiments on outdoor composite polymeric materials
Two suggested techniques1, thermal analysis and infra-red spectrophotometrys are used to characterise the deterioration process caused by ultra-violet radiation on polymeric materials. The suggested mechanism of photo-oxidation is presented. A correlation between the depletion of tracking resistance and the oxidation of the polimeric surface was obtained, which was proportional to aging time. Good agreement was obtained, also, between the infra-red spetra with the thermal analysis of new and aged samples; thus, T.A. and I.R. data are presented as two useful tools for characterising polymeric materials which are aged by U.V. radiation.
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