钙钛矿-硅串联太阳能电池稳定性挑战及可能解决方案综述

M. Z. Hossain, Md. Yakub Ali Khan, Md. Abdul Halim, Nafisa Sultana Elme, Md. Nayeem Hussain
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摘要

钙钛矿-硅串联太阳能电池在提高太阳能电池效率方面显示出巨大的潜力,效率高达25%。然而,这些电池的稳定性仍然是一个重大挑战,必须在它们商业化之前解决。本文综述了钙钛矿-硅串联太阳能电池的稳定性挑战以及解决这些挑战的可能解决方案。主要的稳定性问题包括钙钛矿层的不稳定性、硅层的降解以及层间界面的失效。一种解决方案是使用更稳定的钙钛矿材料,如甲基碘化铅(MAPbI3)或甲脒碘化铅(FAPbI3),它们比传统的钙钛矿材料表现出更好的稳定性。另一种解决方案是使用钝化层,如二氧化钛,以保护钙钛矿层不被降解。另一种解决方案是使用硅异质结(SHJ)太阳能电池,它比传统的硅太阳能电池表现出更好的稳定性。此外,使用封装技术,如使用阻隔层或密封,可以帮助保护串联太阳能电池免受环境退化。为了提高钙钛矿-硅串联太阳能电池的稳定性,必须继续研究开发更稳定的钙钛矿材料、钝化层和封装技术。此外,还需要进一步的研究来了解降解的机制,并开发监测和减轻串联太阳能电池降解的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Review on Stability Challenges and Probable Solution of Perovskite–Silicon Tandem Solar Cells
Perovskite-silicon tandem solar cells have shown great potential in increasing the efficiency of solar cells, with efficiencies reaching as high as 25%. However, the stability of these cells remains a major challenge that must be addressed before they can be commercialized. This review focuses on the stability challenges of perovskite-silicon tandem solar cells and possible solutions to address these challenges. The main stability issues include the instability of the perovskite layer, the degradation of the silicon layer, and the failure of the interfaces between the layers. One solution is to use more stable perovskite materials, such as methylammonium lead iodide (MAPbI3) or formamidinium lead iodide (FAPbI3), which have shown better stability than traditional perovskite materials. Another solution is to use passivating layers, such as titanium dioxide, to protect the perovskite layer from degradation. Another solution is to use silicon heterojunction (SHJ) solar cells, which have shown better stability than traditional silicon solar cells. In addition, the use of encapsulation techniques, such as using a barrier layer or a hermetic seal, can help to protect the tandem solar cell from environmental degradation. In order to improve the stability of perovskite-silicon tandem solar cells, it is important to continue research on the development of more stable perovskite materials, passivating layers, and encapsulation techniques. Additionally, further research is needed to understand the mechanisms of degradation and to develop methods for monitoring and mitigating the degradation of the tandem solar cells.
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