{"title":"核碱基、核苷和核苷酸中氢键的远红外光谱","authors":"B. Fischer, M. Walther, P. Jepsen","doi":"10.1109/THZ.2002.1037593","DOIUrl":null,"url":null,"abstract":"The far-infrared dielectric properties of organic acids and bases in the condensed phase are dominated by hydrogen bonding between the individual molecules. We have investigated the dielectric properties of nucleobases, nucleosides, and nucleotides. We find that at cold temperatures distinct vibrational modes are present in the frequency range 0.1-4 THz. These modes originate from ordered hydrogen bonds between the molecules.","PeriodicalId":143116,"journal":{"name":"Proceedings, IEEE Tenth International Conference on Terahertz Electronics","volume":"76 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2002-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"Far-infrared spectroscopy of hydrogen bonding in nucleobases, nucleosides, and nucleotides\",\"authors\":\"B. Fischer, M. Walther, P. Jepsen\",\"doi\":\"10.1109/THZ.2002.1037593\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The far-infrared dielectric properties of organic acids and bases in the condensed phase are dominated by hydrogen bonding between the individual molecules. We have investigated the dielectric properties of nucleobases, nucleosides, and nucleotides. We find that at cold temperatures distinct vibrational modes are present in the frequency range 0.1-4 THz. These modes originate from ordered hydrogen bonds between the molecules.\",\"PeriodicalId\":143116,\"journal\":{\"name\":\"Proceedings, IEEE Tenth International Conference on Terahertz Electronics\",\"volume\":\"76 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-11-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings, IEEE Tenth International Conference on Terahertz Electronics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/THZ.2002.1037593\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings, IEEE Tenth International Conference on Terahertz Electronics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/THZ.2002.1037593","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Far-infrared spectroscopy of hydrogen bonding in nucleobases, nucleosides, and nucleotides
The far-infrared dielectric properties of organic acids and bases in the condensed phase are dominated by hydrogen bonding between the individual molecules. We have investigated the dielectric properties of nucleobases, nucleosides, and nucleotides. We find that at cold temperatures distinct vibrational modes are present in the frequency range 0.1-4 THz. These modes originate from ordered hydrogen bonds between the molecules.