船用柴油机非热等离子体排放控制系统

W. Balachandran, R. Beleca, N. Manivannan, M. Abbod
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引用次数: 2

摘要

船舶产生的气体和颗粒形式的空气污染物对环境质量有长期影响,并对居住在港口附近或邻近沿海地区的人们造成重大暴露风险。据最近估计,船舶产生的氮氧化物至少占世界总量的15%(超过世界上所有汽车、公共汽车和卡车的总和),温室气体的2.5% -4%,黑碳(BC)的5%,以及全球二氧化硫排放量的3% -7%。目前还没有关于海运对全球挥发性有机化合物和一氧化碳排放量贡献的估计。为了减少船舶对环境的影响,国际海事组织(IMO)最近发布了《防污公约》附则VI的立法指南,其中特别指出,根据修订后的《防污公约》附则VI, eca的船用燃料硫含量限制将从目前的4.50%提高到3.50%,自2012年1月1日起生效;然后逐步提高至0.50%,自2020年1月1日起生效,但不迟于2018年完成可行性审查。从2010年7月1日起,排放控制区(ECAs)对硫氧化物和颗粒物的适用限值从原来的1.50%降至1.00%;从2015年1月1日起进一步降至0.10%。III级控制措施仅适用于2016年以后建造的、在为限制氮氧化物排放而设立的排放控制区(ECA)内运营的指定船舶,II级控制措施适用于这些区域以外的船舶。美国和加拿大通过了国家法规,自2016年起在北美ECA执行IMO第三级当量限制。然而,美国环境保护署(EPA)对第三类船舶的规定参考了国际海事组织的标准。如果IMO排放标准确实推迟,那么从2016年起,Tier III标准将仅适用于悬挂美国国旗的船舶。提出的解决方案之一是船用柴油排放控制的非热等离子体过程。设计并建造了微波与电子束相结合的非热等离子体反应器(NTPR),用于处理船用柴油机废气。为了更好地理解海洋废气/等离子体动力学,建立了一个数值模型。反应器的建模和设计可以承受10kW的MW和EB组合功率,气体流速为200l/s。使用便携式双Testo气体分析仪系统连续监测NOx和SOx的去除,同时通过Labview DAQ系统远程记录和存储所有其他参数(MW功率,EB功率,气体温度/流速等)。该反应器在去除NOx和SOx方面的性能将在一台200千瓦二冲程船用发动机上进行测试。这项研究是DEECON(船用柴油机排放控制创新后处理系统)FP7欧洲项目的一部分。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Non-thermal plasma system for marine diesel engine emissions control
Air pollutants generated by ships in both gaseous and particulate forms, have a long term effect on the quality of the environment and cause a significant exposure risk to people living in proximities of harbors or in neighboring coastal areas. It was recently estimated, that ships produce at least 15% of the world's NOx (more than all of the world's cars, buses and trucks combined), between 2.5-4% of greenhouse gases, 5% black carbon (BC), and between 3-7% of global SO2 output. Estimation of contribution of maritime shipping to global emissions of VOC and CO is not yet available. In order to reduce the environmental footprint of ships, the International Maritime Organization (IMO) recently issued the legislation of Marpol Annex VI guidelines which implies especially the introduction of, inter alia, stricter sulphur limits for marine fuel in ECAs under the revised MARPOL Annex VI, to 3.50% (from the current 4.50%), effective from 1 January 2012; then progressively to 0.50 %, effective from 1 January 2020, subject to a feasibility review to be completed no later than 2018. The limits applicable in Emission Control Zones (ECAs) for SOx and particulate matter were reduced to 1.00%, beginning on 1 July 2010 (from the original 1.50%); being further reduced to 0.10 %, effective from 1 January 2015. The Tier III controls apply only to the specified ships built from 2016 while operating in Emission Control Areas (ECA) established to limit NOx emissions, outside such areas the Tier II controls apply. The United States and Canada adopted national regulations enforcing IMO Tier III equivalent limits within the North American ECA effective 2016. The US Environmental Protection Agency (EPA) rule for Category III ships, however, references the international IMO standards. If the IMO emission standards are indeed delayed, the Tier III standards would be applicable from 2016 only for US flagged vessels. One of the proposed solutions towards marine diesel emission control is the non-thermal plasma process. We designed and built a non-thermal plasma reactor (NTPR) using a combination of Microwave (MW) and Electron Beam (EB) for treatment of marine diesel exhaust gas. A numerical model has been developed to better understand the marine exhaust gas/plasma kinetics. The reactor modelling and design can sustain 10kW of combined MW and EB power with a gas flow rate of 200l/s. The removal of NOx and SOx was continuously monitored using a portable dual Testo gas analyzer system while all other parameters (MW power, EB power, gas temperature/flow rate, etc.) were remotely recorded & stored through a Labview DAQ system. The reactor performance in NOx and SOx removal will be tested on a 200 kW two stroke marine engine. This study is a part of the DEECON (Innovative After-Treatment System for Marine Diesel Engine Emission Control) FP7 European project.
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