面向集成气化燃料电池的阳极支撑平面中温固体氧化物燃料电池建模与仿真

Lu-ning Xu, Li Han, Z. Dong
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引用次数: 0

摘要

利用多种燃料的能力是固体氧化物燃料电池(SOFC)在固定式电力应用中的优势之一,当与适当的煤气炉和气体转化炉相结合时,也是通过集成气化燃料电池(IGFC)应用来使用煤炭的有前途的解决方案。近年来,阳极支撑的平面SOFC因其更高的功率密度和更低的工作温度而成为SOFC商业化的一个有希望的候选材料。在工作中,SOFC和市售的煤气化炉和转化炉在MATLAB中建模。利用电化学和反应动力学方程建立了燃料电池和重整器模型,并根据经验数据确定了参数。集成的半经验IGFC模型和仿真指导了给定SOFC在IGFC应用中选择合适的煤气炉和转化炉。用两种不同的、具有代表性的气化炉和不同的合成气作为SOFC的燃料,进行了试验,以证明其性能差异和确定最佳SOFC的方法,气化炉-转化炉匹配。仿真结果与文献数据吻合较好。这项工作有助于开发新的综合煤气化和SOFC系统,以提高能源效率和减少排放。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Modeling and simulation of anode-supported planar intermediate temperature solid oxide fuel cell for integrated gasification fuel cell application
The capability of exploiting various fuels is one of the advantages of solid oxide fuel cells (SOFC) on stationary power application, and also a promising solution for using coal through the integrated gasification fuel cell (IGFC) application when combined with a proper coal gasifier and gas reformer. Recently, the anode supported planar SOFC becomes a promising candidate for SOFC commercialization due to its higher power density and lower operation temperature. In the work, SOFC and commercially available coal gasifiers and reformer are modeled in MATLAB. The fuel cell and reformer models are built using electrochemical and reaction kinetics equations with empirical data determined parameters using literature data. The integrated semi-empirical IGFC model and simulation guide the selection of appropriate coal gasifier and reformer for a given SOFC in IGFC application. Tests have been done using two different and representative gasifiers with different syngas to fuel the SOFC, to demonstrate the performance difference and the method for identify the best SOFC, gasifier-reformer match. Simulation results showed good consistency with literature data. The work contributes new integrated coal gasification and SOFC system development for improved energy efficiency and emission reduction.
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