不同温度下油批式聚乙烯和聚乙烯塑料废弃物的热解特性

Indah Kusuma Dewi, A. Prasetya, Supranto
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引用次数: 1

摘要

目前正在努力利用聚乙烯(PE)和聚苯乙烯(PS)塑料废物,将其转化为燃料或石油。一种可以使用的技术是热解。本研究旨在(1)从不同温度下的聚乙烯(PE)和聚苯乙烯(PS)塑料废弃物热解结果中确定油的数量和特性,包括物理特性(比重、热值、闪点、倾点、运动粘度)和化学特性(油的组成化合物);(2)确定与热解油的质量和数量相关的过程热解的最佳条件;(3)确定热解法处理PE和PS塑料废弃物的潜力。本研究中使用的材料是聚乙烯(塑料袋)和聚苯乙烯/聚苯乙烯泡沫塑料(用于水果或蔬菜)塑料废物。选取的温度变化分别为T = 400oC、450oC和500oC。对热解油进行称重,测量其体积,得到v/wo和产率。结果表明:以v/wo (ml/g)为单位,聚乙烯(PE)废塑料在400、450和500℃温度下的热解油量分别为0.3429 ml/g;0.5129 ml / g;和0.199 ml/g,而聚苯乙烯(PS)废塑料在400、450和500℃下的结果分别为0.89 ml/g;0.905 ml / g;0.915 ml/g。在400、450和500℃温度下,聚乙烯(PE)废塑料产率热解油的结果分别为33.33 wt%;38.61 wt %;和15.55 wt%,而聚苯乙烯(PS)塑料垃圾在400、450和500℃分别为80.94 wt%;79.79 wt %;80.14% wt%。而PE塑料热解油在400℃时的特性更接近煤油,在450℃和500℃时的特性更接近柴油。PS塑料在400、450和500℃温度下的热解油结果更接近于汽油的特性。在450℃条件下,PE塑料的热解量与热解油的最佳条件有关,此时的v/wo和产率分别最高为0.5129 ml/g和38.16 wt%,而PS的热解量则无最佳条件。因为,尽管温度升高,石油产量相对稳定。基于技术分析,采用热解法处理PE和PS塑料废弃物具有社会效益,是可行的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
CHARACTERISTICS OF PYROLYSIS OIL BATCH POLYETHYLENE AND POLYSTHYRENE PLASTIC WASTE AT VARIOUS TEMPERATURES
Efforts are being carried out in order to utilize polyethylene (PE) and polystyrene (PS) plastic waste by converting them into fuel or oil. One technology that can be used is pyrolysis. This study aims to (1) determine the quantity and the characteristics of oil from the results of pyrolysis polyethylene (PE) and polystyrene (PS) plastic waste at various temperatures which include characteristics of physics (specific gravity, heating value, flash point, pour point, and kinematic viscosity) and chemical characteristics (composition compounds in oil), (2) determine the optimal conditions of process pyrolysis related to the quality and quantity of oil by pyrolysis, and (3) determine the potential treatment of PE and PS plastic waste by pyrolysis method.The materials used in this study were the type of polyethylene (plastic bags) and polystyrene/styrofoam (for fruits or vegetables) plastic waste. The selected temperature variations are T = 400oC, 450oC, and 500oC. Pyrolysis oil was weighed and measured its volume to obtain v/wo and yield.The results showed that the quantity of pyrolysis oil from polyethylene (PE) plastic waste at temperatures of 400, 450, and 500oC based on v/wo (ml/g) respectively were 0.3429 ml/g; 0.5129 ml/g; and 0.199 ml/g while the results of polystyrene (PS) plastic waste at temperatures of 400, 450, and 500oC respectively were 0.89 ml/g; 0.905 ml/g; and 0.915 ml/g. The results of pyrolysis oil based on yield of polyethylene (PE) plastic waste at temperatures of 400, 450, and 500oC respectively were 33.33 wt%; 38.61 wt%; and 15.55 wt% while polystyrene (PS) plastic waste at temperatures of 400, 450, and 500oC respectively were 80.94 wt%; 79.79 wt%; and 80.14 wt%. While the characteristics shown by the results of pyrolysis oil from PE plastic with a temperature of 400oC were closer to kerosene while at temperatures of 450 and 500oC were closer to the characteristics of diesel fuel. As for pyrolysis oil results of PS plastic with temperatures of 400, 450, and 500oC were closer to the characteristics of gasoline. Optimal conditions of pyrolysis oil related to the quantity of pyrolysis of PE plastic at a temperature of 450oC was obtained when the highest of v/wo and yield respectively were 0.5129 ml/g and 38.16 wt%, while for the pyrolysis of PS did not have any optimal conditions. For, oil produced was relatively constant despite the increasing temperatures. Based on technical analysis, handling PE and PS plastic waste using pyrolysis methods provides benefits to society making it feasible to do.
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