葡萄、果酒和浆果酒的研究及其造假检测

A. Klimchuk, Olha Bui, Jose Manuel Colodras, O. Pashkova
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摘要

对葡萄、水果和浆果酒进行了研究,以便通过添加合成染料来检测伪造的迹象。值得注意的是,在为研究提供的未知液体的分析(检查)过程中,专家必须首先确定这些物体的性质。只有在确定了物体在其实际状态下的特征频谱之后,才有可能找到答案。通过实验建立了葡萄、果酒和浆果酒的有机酸成分表;证明了在分析样品中测定有机酸的可能性;给出了添加染料的葡萄酒伪造的迹象,并提出了检测方法。法医鉴定的基础要求之一是必须通过至少两种可靠的方法来确认分析结果,因此,在拟议的科学研究中,考虑使用薄层色谱法、红外光谱法和添加碱性溶液的方法来研究某些合成染料。通过色谱法可以检测到葡萄、水果和浆果酒中特定的有机酸,从而可以在确定葡萄酒性质的过程中将其作为鉴别标志。真正的葡萄酒样品中含有高浓度的酒石酸,这种酸只存在于葡萄产品中。事实证明,一套研究葡萄、水果和浆果酒的方法,旨在确定合成染料的存在和鉴定,使人们有可能回答有关通过着色伪造酿酒产品的审查所提出的问题。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Research on Grape and Fruit and Berry Wines and Detection of their Falsification
Grape and fruit and berry wines were studied in order to detect signs of their falsification by adding synthetic dyes. It is noted that in the process of analysis (examination) of unknown  liquids provided for research, specialists must first of all establish the nature of such objects. It is possible to find out only after identifying the spectrum of features characteristic of the object in its actual state. The list of organic acids, which are components of grape and fruit and berry wines, was established experimentally; the possibility of determining organic acids in the analyzed samples was proven; signs of falsification of wines with the addition of dyes were given and methods of their detection were proposed. One of the cornerstone requirements for forensic examination is the mandatory confirmation of the results of analysis by at least two reliable methods, therefore, in the proposed scientific research, options for the study of some synthetic dyes using methods of thin- layer chromatography, IR spectroscopy and the addition of alkaline solutions are considered. It was established that the set of specific organic acids in grape and fruit and berry wines, which can be detected using the chromatography method, makes it possible to use them as differential signs in the process of establishing the nature of the wine. Samples of real grape wines are marked by a high concentration of tartaric acid, which is present only in grape products. It has been proven that the set of methods for studying grape and fruit and berry wines, aimed at determining the presence and identification of synthetic dyes, makes it possible to answer the questions posed by the examination on the falsification of winemaking products by coloring.
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