介孔基质中支持的氧化铁纳米颗粒去除水中的砷

G. Ramírez-Jiménez, M. Rosales-López, A. Larios-González, V. Palos-Barba, J. Mendiola, R. Nava
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引用次数: 0

摘要

通过饮用用受污染的水灌溉的水或食物摄入砷一直是世界各地的一个健康问题。本文采用溶胶-凝胶法合成了介孔二氧化硅作为载体材料,并在磁场的作用下缩短了制备时间,SBA-15vg。通过对合成方法的改进,将形成溶胶的时间从24小时缩短到5小时,同时保持了SBA-15的结构和性质相似,以及形态特征,比表面积大于800 m2/g。在该体系中,Fe/SBA-15vg掺入到介孔材料中,不同种类的氧化铁纳米颗粒作为活性位点吸附无机as离子,这是由于报道的与铁种类的亲和力。采用原子吸收光谱法对墨西哥瓜纳华托地区的井水样品进行了砷吸附实验。结果表明,Fe/SBA-15vg体系可以降低砷浓度较低、镉、铅、铬等重金属存在的水中As (V)的浓度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Iron oxides nanoparticles supported in a mesoporous matrix for the arsenic remotion of water
Intake of arsenic (As) through the consumption of water or food irrigated with contaminated water has been a health problem around the world. In this work, mesoporous silica as a support material was synthesized by the sol-gel method with the application of a magnetic field reducing the time of its preparation, SBA-15vg. This modification to the synthesis method reduced the sol formation stage from 24 to 5 h while maintaining the textural and properties similar as well as the morphological properties of the SBA-15 and a specific surface area of more than 800 m2/g. In the system Fe/SBA-15vg incorporation into the mesoporous material of different species of iron oxide nanoparticles acting as active sites for the adsorption of inorganic As ions due to the reported affinity with iron species. Arsenic adsorption experiments were prepared in well water samples from a site located in Guanajuato, Mexico, through atomic absorption spectroscopy. The results showed that the Fe/SBA-15vg system could reduce the concentration of As (V) in water with low arsenic concentration and the presence of other heavy metals like cadmium, lead, and chromium.
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