粉煤灰活化稳定铅污染土壤及其溶液

Mabrouk Hassan Arhoma
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引用次数: 1

摘要

通过在铅溶液中加入逐渐下降的NaOH,考察pH对金属污染溶液去除的影响,观察pH的增加,并采用ICP测量铅溶液的浓度。采用活化粉煤灰粉(PFA)作为稳定材料。研究铅的浸出行为,将5克土壤与0.1克稳定材料彻底混合,放入聚丙烯容器中,其中50ml去离子水;将混合物在平板振动筛上摇匀2h,然后用What man 542号滤纸过滤。采用电感耦合等离子体原子发射光谱法测定滤液中铅的浓度。添加PFA的效果是将铅的释放量降低到较高pH值时无法检测到的水平。对留存在滤纸上的土壤样品的x射线衍射分析结果表明,土壤中形成了硫酸铅和碳酸铅。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ACTIVATION OF FLY ASH TO STABILISE LEAD CONTAMINATED SOILS AND SOLUTIONS
The role of pH on removal of metal contaminated solution was investigated by adding gradually drops of NaOH to lead solutions, the increase of the pH was observed and concentration of lead solution was measured by using ICP. The activated \ pulverised fly ash (PFA) was used as stabilizing material. The leaching behaviour of lead was investigated using 5 grams of the soil thoroughly mixed with 0.1g of the stabilising material in a polypropylene container to which 50ml of either deionised water; the mixture was shaken on a flat bed shaker for 2h, and then filtered using a What man No 542 filter paper. The lead concentration in the filtrate was determined by inductively coupled plasma-atomic emission spectrometry (ICP). The effect of adding PFA was a reduction in Pb released to an undetectable level at higher pH levels. Results from the analysis of X-ray diffraction on the soil samples retained on the filter paper showed the formation of lead sulphate and lead carbonate.
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