硫化铁化学溶解剂在水井中的应用

Nasser M. Al-Hajri, Sulaiman T. Ureiga, Muhammad Imran Javed, Saleh J Marri
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摘要

本文将介绍一种具有开创性的硫化铁(FeS)化学溶解剂。该新型化学溶解剂可用于油气井除垢。然而,本文的特定范围是概述在水井中成功部署FeS溶解剂的操作井干预工作流程。井筒中硫化铁结垢的存在对油田运营商来说是一个挑战。与碳酸钙等其他常见的水垢不同,FeS水垢不易溶于盐酸(HCl), FeS/HCl反应产生危险的硫化氢作为反应产物。因此,为了恢复井筒的可达性,油田作业者采用机械除垢的方法对FeS进行除垢。机械除垢的缺点包括成本高,需要回排井下磨铣,并且可能损坏井下管柱。另外,本文中描述的新型化学物质可以有效地去除井眼结垢,而不会使油田作业人员遭受机械除垢所带来的挫折。本文将概述执行旗舰除垢操作的操作步骤。作业步骤包括作业前诊断、作业设计和突发事件,以及预期结果和结果。所提出的FeS溶解剂已成功满足所有实验室和现场标准,以除硫化铁结垢并提高井的注入能力。与化学除垢前相比,使用FeS溶解剂可以使总注入速率提高67%。该化学品的其他实际好处包括,在机械除垢不能成功恢复井筒通道的情况下,避免了钻机修井作业,即拔出和更换井下油管。这种新型化学物质通过降低硫化氢再生、非友好化学物质对地层的损害以及腐蚀对井下设备的损害等风险,实现了更安全的除垢作业。该化学品还具有溶解碳酸盐的能力,用于近井清理。与15%的盐酸相比,该溶解剂的溶解能力提高了70%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Iron Sulfide Chemical Dissolver Deployment in Water Wells
This paper will introduce a pioneering Iron Sulfide (FeS) chemical dissolver. The novel chemical dissolver can be used for descaling applications in oil and gas wells. However, the particular scope of this paper would be to outline an operational well intervention workflow for a successful deployment of FeS dissolver in water wells. Iron sulfide scale presence in the wellbore is challenging to oilfield operators. Unlike other common scale types, such as Calcium Carbonates, FeS scale does not dissolve easily in Hydrochloric Acid (HCl) and the FeS/HCl reaction produces the dangerous Hydrogen Sulfide as a reaction product. Accordingly, oilfield operators resort to mechanical descaling of the FeS in order to restore wellbore accessibility. Mechanical descaling has disadvantages that include high cost, the need to flowback downhole milling returns, and possible damage to downhole tubulars. Alternatively, the novel chemical described in this paper can be used to effectively descale the wellbore without exposing the oilfield operator to the setbacks that could encountered from mechanical descaling. This paper will outline operational steps to execute a flagship descaling operation. The operational steps include pre-job diagnostics, job design and contingencies, as well as expected results and outcomes. The proposed FeS dissolving chemical has successfully met all laboratory and field criteria to descale iron sulfide scale and stimulated well injectivity. The deployment of the FeS dissolver can result in 67 % increase in overall well injection rate compared to pre-chemical descaling rate. Other tangible benefits to this chemical include avoidance of rig workover operations to pull and replace downhole tubing in cases where mechanical descaling was not successful in restoring wellbore access. The new chemical allows for conducting safer descaling operation by reducing risks associated with reproduction of hydrogen sulfide, formation damage from non-friendly chemicals, and downhole equipment damage by corrosion. The chemical also has the ability to dissolve carbonates for near wellbore cleanup. The dissolver has a 70 % enhanced dissolving ability comparing to 15% HCl.
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