脉冲电容器用合成液体介质电性能的改进

Abdullayeva Maya Yadigar, I. Habibov
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引用次数: 1

摘要

增加发电量不仅可以通过建设发电厂,而且还可以通过开发新的能源。如何保证电容器在超过50- 200mv的电场强度下工作的可靠性,是现代电气工程的难题之一。在国内外电容器行业中,对于重脉冲模式,采用蓖麻油(CO)作为液体浸渍剂。蓖麻油是电容器中普遍使用的浸渍液,开发一种替代蓖麻油的生产方法是电气工业中迫切需要解决的问题。因此,我们开发了一种生产乙酰氧基甲基-w的方法。己基-邻二甲苯,其电物理特性使其成为一种环保的、有前途的天然蓖麻油替代品。然而,有一个稳定的问题,因为酯类化合物(作为电容器中的浸渍液体)有一个缺点,这包括它们对光水解和大气效应的敏感性。酯表现出相对于空气高达200°С的高稳定性,因此,通过添加抗氧化剂来抑制是必要的,这不是新的。本文研究了酯-乙酰氧基甲基-仲己基-邻二甲苯的基本电物理性质;其纯化及稳定方法。选择热氧化稳定吸附法去除介质中导电杂质。研究了乙酰氧基甲基-仲己基-邻二甲醚酯的电物理特性,以及用氧化铝提纯的方法,以及在氧化铝上含0.2%钯的催化剂上加氢和使用添加剂NG-2246稳定的方法。研究的结果是,有可能获得具有改进的电物理参数的酯
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Improvement of the Electrical Properties of Synthetic Liquid Dielectric for Pulse Capacitors
An increase in electricity generation is possible not only through the construction of power plants, but also through the creation of fundamentally new energy sources. One of the problems of modern electrical engineering is to ensure the reliability of the operation of capacitors at electric field strengths exceeding I50-200MV. In the domestic and foreign capacitor industry, for heavy pulse modes, castor oil (CO) is used as a liquid impregnation. The development of a method for producing a substitute for natural castor oil, which is a universal impregnating liquid in capacitors, is an urgent problem in the electrical industry. Thus, we have developed a method for the production of acetoxymethyl-w.hexyl-o-xylene, the electrophysical properties of which make it possible to use it as an environmentally friendly and promising substitute for natural castor oil. However, there was a problem of stabilization, since compounds of the ester type have (as impregnating liquids in capacitors) a disadvantage, which consists in their sensitivity to light hydrolysis and atmospheric effects. Ester exhibits high stability with respect to air up to 200 °С, therefore, inhibition by the addition of antioxidants is required is not new. In this work developed the basic electrophysical properties of the ester-acetoxymethyl-secondary hexyl-o-xyleole; methods for its purification and stabilization. There were chosen the adsorption method of thermo-oxidative stabilization to clean dielectric fluid from conductive impurities. As a result of the electrophysical characteristics of the acetoxymethyl-secondary hexyl-o-xyleole ester, as well as the method of its purification using alumina, and hydrogenation on a catalyst representing 0.2 % palladium on alumina and stabilization using additives NG-2246. As a result of the research, it was possible to obtain an ester with improved electrophysical parameters
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