热激发放电对rho弛豫非晶PET结晶的影响

J. Belana, P. Colomer
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引用次数: 0

摘要

非晶态PET(聚对苯二甲酸乙二醇酯)驻极体一侧金属化,电晕在T/sub p/>70℃下带电,在20℃~ 105℃之间表现出α、rho /sub 1/和rho /sub 2/三个弛豫。rho /sub 2/的来源是电极注入的自由电荷,而rho /sub 1/可能与均匀体机制有关。p/sub 1/峰位于两侧金属化的驻极体中,在73°C和79°C之间,只在等温阶段极化,因此在T/sub p/>79°C时,它与rho重叠。在两侧金属化的非晶态PET样品中,热刺激结晶表明rho /sub 1/随结晶度的变化而变化,成为结晶PET的α /sub c/弛豫
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Concerning the rho relaxation amorphous PET crystallization by thermally stimulated discharge
The thermal depolarization of amorphous PET (polyethylene terephthalate) electrets metallized on one side and corona charged at T/sub p/>70 degrees C exhibits, between 20 degrees C and 105 degrees C, three relaxations: alpha , rho /sub 1/ and rho /sub 2/. The origin of rho /sub 2/ is free charge injected from the electrodes, while rho /sub 1/ could be associated with a uniform bulk mechanism. The p/sub 1/ peak has a been located in electrets metallized on both sides and polarized, between 73 degrees C and 79 degrees C, only in the isothermic phase, so that at T/sub p/>79 degrees C it overlaps with rho . The stimulated crystallization by thermal steps in amorphous PET samples, metallized on both sides, indicates that rho /sub 1/ changes with the crystallinity and becomes the alpha /sub c/ relaxation of the crystalline PET.<>
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