关于硅明的改性

E. I. Marukovich, V. Stetsenko, A. Stetsenko
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引用次数: 0

摘要

结果表明,硅、铝、硅改性基本产物的基本晶胞不符合丹科夫-科诺别夫斯基的结构和尺寸对应原理。改性元素B、Sr、P显著提高了液态硅明的表面能,而Zr和Ti对其几乎没有影响。硅明的修饰是一个纳米结构的过程。Ti, Zr, B形成金属间化物,使吸附的氢原子脱除杂质,形成铝纳米晶体。磷原子溶解在硅中,从吸附的氧中提炼出硅纳米晶体。钠和锶在液态硅明中形成乳状和胶体,保护α -和β - si共晶微晶不受氢分子的脱晶作用。这些过程增加了枝晶微晶α -和β - si相结晶中心的浓度,使枝晶微晶更具分支性和致密性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
On modification of silumins
It has been shown that the elementary crystal cells of the basic products of modification of silumins, aluminum and silicon do not correspond to the principle of structural and dimensional correspondence of Dankov – Konobeevsky. Modifying elements B, Sr, P significantly increase the surface energy of liquid silumins, and Zr and Ti practically do not affect it. Modification of silumins is a nanostructured process. Ti, Zr, B form intermetallides that refine aluminum nanocrystals from demodifying adsorbed hydrogen atoms. Phosphorus, atomically dissolving in silumin, refiners silicon nanocrystals from adsorbed oxygen. Na and Sr form an emulsion and colloid in liquid silumin, which protect eutectic microcrystals of α‑and βSi‑phases from demodifying molecular hydrogen. All these processes increase the concentration of crystallization centers of dendritic microcrystals α‑and βSi‑phase, make them more branched and compact.
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