kesterite基薄膜太阳能电池面临的挑战综述

P. Dale, Katja Hoenes, J. Scragg, S. Siebentritt
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引用次数: 33

摘要

文献报道的最好的kesterite sulfide Cu2ZnSnS4和selenide Cu2ZnSnS4薄膜太阳能电池器件的性能和光电流光谱与它们的类似的黄铜矿CulnS2和CulnSe2器件进行了比较。从(i)相组成和形貌(ii)光电性能和(iii)层界面等方面分析了kesterite性能变差的原因。提出了一种新的电沉积退火工艺来制备Cu2ZnSnS4吸收层,该吸收层的功率转换效率可达3.2%以上。此外,还首次获得了含有缺陷的Cu2ZnSnS4单晶的光致发光光谱。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A review of the challenges facing kesterite based thin film solar cells
The best literature reported kesterite sulfide Cu2ZnSnS4 and selenide Cu2ZnSnS4 thin film solar cell device performance and photocurrent spectra have been compared with their analogous chalcopyrite CulnS2 and CulnSe2 devices. Reasons for the kesterites worse performance have been analyzed in terms of (i) phase composition and morphology (ii) opto-electronic properties and (iii) layer interfaces. A new electrodepositon and annealing process is presented for producing Cu2ZnSnS4 absorber layers that gave a highest power conversion efficiency of over 3.2 %. Furthermore photoluminescence spectra of Cu2ZnSnS4 single crystals showing defect related is presented for the first time.
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