{"title":"花生籽油合成丙烯酸酯环氧化生物基树脂","authors":"Obieogu Nwosu, F. Aguele, L. Chiemenem","doi":"10.5937/poljteh2104049n","DOIUrl":null,"url":null,"abstract":"In this study, groundnut seed oil was epoxidized in situ using hydrogen peroxide (30%) and formic and acetic acid. The reaction conditions were monitored at a temperature of 70oC, stirring speed of 750 rpm and time of 6 hours. After epoxidation, a further modification was done using acrylic acid in the presence of hydroquinone at a temperature of 120oC. Comparatively, peroxyformic acid performed more effectively than the peroxyacetic acid during epoxidation with an iodine value (26.4 gl/100g oil) and oxirane content(3.27%). FTIR analysis of the raw, epoxidized, and acrylated groundnut seed oil indicates that they were suitably functionalized.","PeriodicalId":281326,"journal":{"name":"Poljoprivredna tehnika","volume":"70 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Synthesis of acrylated epoxidized biobased resin from groundnut seed oil\",\"authors\":\"Obieogu Nwosu, F. Aguele, L. Chiemenem\",\"doi\":\"10.5937/poljteh2104049n\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this study, groundnut seed oil was epoxidized in situ using hydrogen peroxide (30%) and formic and acetic acid. The reaction conditions were monitored at a temperature of 70oC, stirring speed of 750 rpm and time of 6 hours. After epoxidation, a further modification was done using acrylic acid in the presence of hydroquinone at a temperature of 120oC. Comparatively, peroxyformic acid performed more effectively than the peroxyacetic acid during epoxidation with an iodine value (26.4 gl/100g oil) and oxirane content(3.27%). FTIR analysis of the raw, epoxidized, and acrylated groundnut seed oil indicates that they were suitably functionalized.\",\"PeriodicalId\":281326,\"journal\":{\"name\":\"Poljoprivredna tehnika\",\"volume\":\"70 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Poljoprivredna tehnika\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.5937/poljteh2104049n\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Poljoprivredna tehnika","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.5937/poljteh2104049n","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis of acrylated epoxidized biobased resin from groundnut seed oil
In this study, groundnut seed oil was epoxidized in situ using hydrogen peroxide (30%) and formic and acetic acid. The reaction conditions were monitored at a temperature of 70oC, stirring speed of 750 rpm and time of 6 hours. After epoxidation, a further modification was done using acrylic acid in the presence of hydroquinone at a temperature of 120oC. Comparatively, peroxyformic acid performed more effectively than the peroxyacetic acid during epoxidation with an iodine value (26.4 gl/100g oil) and oxirane content(3.27%). FTIR analysis of the raw, epoxidized, and acrylated groundnut seed oil indicates that they were suitably functionalized.
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