混杂补强填料增强聚苯乙烯复合材料的力学和电学性能表征

Tamer N. Abdalla, Ahmed F. Hasan, Ansam A. Hashim
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引用次数: 1

摘要

导电性聚合物在现代电子器件中扮演着重要的角色,在通信和生物传感器中发挥着至关重要的作用。这种类型的材料提供了设备的重量明显减少,它也有一个环境兼容性。导电聚合物复合材料是目前在电子应用中具有许多优点的一种很有前途的替代材料。聚酯被用作基体,铜-锡/锌的颗粒与铜短导线被认为是导电填料。采用不同的填充材料(Cu- Tin /Zink - Polyester和Cu- Tin /Zink - Cu- short wires / Polyester)制备了A组和B组,其重量分数百分比高达50%。采用滑移铸造复合工艺制备矩形和圆柱形试样;之后,样品在室温下固化48小时。对两种混合物制成的样品进行了密度、极限拉伸强度和扫描电镜测试。对所有样品进行交流电导率测试,频率范围为50 Hz至50 MHz,测量介电损耗因子和电导率。从研究中发现,填充粉几乎证明了更好的极限强度行为,峰值确定在30% wt.,而超过40% wt.的短线会导致抗拉强度急剧下降。结果表明,短线填充车的电导率提高约50%;与仅使用颗粒填料相比。微观结构分析结果表明,金属粉末短导线可以提供一个连接网络,以提高聚合物基体的导电性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Characterization of Mechanical and Electrical Properties of Polystyrene Composite Reinforced by Hybrid Reinforcement Filler
Nowadays, electrically conductive polymer plays some important roles in the modern electronic devices because the crucial importance in telecommunication and biosensors. This type of materials offers an obvious decrease in the weight of the devices and it also has an environmental compatibility. A conductive polymer composite is promising alternative materials that has several advantages in the electronic applications currently. Polyester was used as a matrix, and copper –Tin /Zink inform of particulates with Copper short wires were considered electrically conductive fillers. The study prepared two groups (A and B) using different filler materials (Cu- Tin /Zink - Polyester and Cu- Tin /Zink –Cu- short wires / Polyester) with a weight fraction percentage of up to 50%. A composite processing method was slip casting to produce rectangular and cylindrical samples; after that samples were cured at room temperature for 48 hrs. Produced samples from both mixed were tested for density, ultimate tensile strength and scan electron microscope. AC conductivity test were performed for all samples using a frequency range from 50 Hz to 50 MHz to measure the dielectrically loss factor and electrical conductivity.  From the study, it has been found that filler powder almost proved better ultimate strength behavior, and the peak value was determined at 30% wt., while short wires above 40 % wt. can cause a dramatic reduction in tensile strength. The results revealed that short wires filler van improves the electrical conductivity by approximately 50%; when compared with using particulate filler only. The result from the microstructure showed that short wires with metals powder could provide a connected network for improving the conductivity in the polymer matrix.
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