聚合物中的孤子非线性薛定谔方程和微波吸收光谱

Zhang Kaixi, Zhao Qing-xun
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引用次数: 1

摘要

利用高分子材料的微波吸收光谱(电子自旋共振),应用孤子理论的方法研究了孤子、电子和声子的行为,解释了聚合物的断裂,并应用电子自旋共振谱观察了聚合物中应力引起的键断裂。结果表明,孤子可能只在局部效应下被激发,在分子链末端发生波动(如断裂)时释放的能量会形成孤子,用孤子计算的结果与实测结果一致。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Soliton nonlinear Schrodinger equation and microwave absorption spectroscopy in polymers
Using microwave absorption spectroscopy (electron spin resonance) in polymer materials the methods of soliton theory are applied to investigating behaviors of solitons, electrons and phonons to explain polymer fracture and electron spin resonance spectrometer observations of stress induced bond rupture in polymers. The results show that solitons may be excited only be local effect the energy released during a fluctuation (such as rupture) taking place at the end of a molecular chain will form a soliton, and our results calculated by solitons are in agreement with measurement.
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