新兴绿色技术需求下铝土矿钪的潜在富集

Adinda Ramadhani Haka Putri, L. D. Setijadji, D. Sunjaya
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引用次数: 0

摘要

钪(Sc)已成为重要的原材料之一,目前主要用于生产钪铝合金和固体氧化物燃料电池(SOFCs)。由于钪资源的稀缺,迫切需要发现新的潜在的钪资源,以满足供需。铝土矿是钪的可能来源之一。塔延地区是西加里曼丹红土带的一部分,由于花岗岩类岩石的蚀变,即铝土矿,在印度尼西亚具有钪资源的潜力。本研究通过岩石学、XRD、XRF、ICP-MS和SEM-BSE-EDS等实验室分析,对研究区钪的潜在富集进行了综合地质和赋存模式研究。我们的研究表明,铝土矿样品的凝块结构以铁和氢氧化铝为主。矿石由三水铝石和针铁矿组成。钪浓度分析结果为50.9 ppm。系统的SEM-EDS图谱证实了钪的存在,主要是由于Sc3+取代了Fe3+和Al3+。Sc在针铁矿中被寄存,其中Sc3+在针铁矿晶格中取代Fe3+。Sc3+也取代了Al3+。了解钪在铝土矿中的富集,有望为满足绿色技术发展对关键材料的需求开辟新的可能性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Potential Enrichment of Scandium in Bauxite Deposit for the Emerging Green Technology Needs
Scandium (Sc) becomes one of critical raw materials as principal uses are now in the production of scandium-aluminum alloys and also in Solid Oxide Fuel Cells (SOFCs). Scarcity of scandium resources has led the urgency to discover new potential sources of scandium to meet the supply and demand. One of the possible sources of scandium is from bauxite deposit. Tayan area is part of West Kalimantan laterite belt with the potency for scandium resources in Indonesia as a result of the altered granitoid rocks, namely bauxite. This study presents integrated geological and modes of occurrences study to elucidate the potential enrichment of scandium in the study area including through several laboratory analyses: petrography, XRD, XRF, ICP-MS, and SEM-BSE-EDS. Our study concludes that the concretion textures of bauxite samples are dominated by Fe and Al oxide-hydroxide. The ore is composed of gibbsite and goethite. The result of scandium concentration analysis is equal to 50.9 ppm. Systematic SEM–EDS mapping confirms the presence of scandium as mainly from substitution of Fe3+ and Al3+ by Sc3+. Sc is hosted in goethite, where Sc3+ substitutes Fe3+ in goethite crystal lattice. Sc3+ also substitutes Al3+ in gibbsite crystal lattice. Understanding the enrichment in which scandium occurs in bauxite deposit will hopefully open the new possibility to meet the needs for critical materials for green technology development.
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