{"title":"阳离子钌(II)配合物的合成、结构及其对醛酮转移加氢的催化活性","authors":"Bhattacharjee","doi":"10.2139/ssrn.3639522","DOIUrl":null,"url":null,"abstract":"A new cationic ruthenium(II) complex, [Ru(PPh 3 )(CH 3 CN) 2 LCl]Cl·5CHCl3 {L = N-(diphenylphosphino)pyridin-2-amine} has been synthesized and structurally characterized. The complex is an efficient catalyst for the transfer hydrogenation aldehydes and ketones. It can catalyze intramolecular transfer hydrogenation.","PeriodicalId":399389,"journal":{"name":"Inorganic Chemistry eJournal","volume":"134 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Structure of a Cationic Ruthenium(II) Complex and It's Catalytic Activity Towards Transfer Hydrogenation of Aldehydes and Ketones\",\"authors\":\"Bhattacharjee\",\"doi\":\"10.2139/ssrn.3639522\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new cationic ruthenium(II) complex, [Ru(PPh 3 )(CH 3 CN) 2 LCl]Cl·5CHCl3 {L = N-(diphenylphosphino)pyridin-2-amine} has been synthesized and structurally characterized. The complex is an efficient catalyst for the transfer hydrogenation aldehydes and ketones. It can catalyze intramolecular transfer hydrogenation.\",\"PeriodicalId\":399389,\"journal\":{\"name\":\"Inorganic Chemistry eJournal\",\"volume\":\"134 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry eJournal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2139/ssrn.3639522\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry eJournal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2139/ssrn.3639522","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and Structure of a Cationic Ruthenium(II) Complex and It's Catalytic Activity Towards Transfer Hydrogenation of Aldehydes and Ketones
A new cationic ruthenium(II) complex, [Ru(PPh 3 )(CH 3 CN) 2 LCl]Cl·5CHCl3 {L = N-(diphenylphosphino)pyridin-2-amine} has been synthesized and structurally characterized. The complex is an efficient catalyst for the transfer hydrogenation aldehydes and ketones. It can catalyze intramolecular transfer hydrogenation.
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