(CaO+MgO)/SiO2摩尔比下氧化锆对硅酸钙镁陶瓷生物活性和力学性能的影响

A. Amin, E. Ewais, Y. Ahmed, Eman A. Ashor, U. Hess, K. Rezwan
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引用次数: 5

摘要

研究了在(CaO-MgO)/SiO2摩尔比接近统一的钙-镁-二氧化硅体系中添加不同量的氧化锆(5 wt %、15 wt %和25 wt %)制备的新型陶瓷复合材料。这些系统粉末形成并在1310±20°C下烧制2小时。测定了复合材料的相组成、显微组织和物理力学性能。在模拟体液(SBF)中浸泡7天后,采用SEM-EDS分析其羟基磷灰石(HA)形成能力,考察其体外生物活性。结果表明,所有复合材料表面都有HA形成的开端。然而,含5 wt % ZrO2的复合材料明显倾向于花椰菜形态典型的HA形成能力。所制备的生物活性复合材料的维氏硬度和断裂韧性分别为~3 Gpa和~2 Mpa。分别m1/2。含有5 wt % ZrO2的陶瓷复合材料的性能与人类皮质骨的性能非常相似,可能被提名为植入材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Zirconia Effect on the Bioactivity and the Mechanical Properties ofCalcium Magnesium Silicate Ceramics at (CaO+MgO)/SiO2 Molar RatioClose to Unity
New ceramic composites from calcia-magnesia-silica system at a molar ratio of (CaO-MgO)/SiO2 closes to the unity and the addition of different amounts of zirconia (5 wt %, 15 wt % and 25 wt %) have been investigated. These systems powders were formed and fired at 1310 ± 20°C for 2 hr. Phase composition, microstructure, physical and mechanical properties of these composites were determined. The in-vitro bioactivities of these sintered composites were investigated by analysis of their ability for the formation of hydroxyapatite (HA) using SEM-EDS after their soaking in the simulated body fluid (SBF) for 7 days. The findings indicated that beginning of HA formation on the surface of all investigated composites. However, the composite containing 5 wt % ZrO2 gave clear tendency toward the formation-ability of HA typical to cauliflower morphology. The mechanical properties of the promised bioactive composite in term of Vickers hardness and fracture toughness were ~3 Gpa and ~2 Mpa. m1/2, respectively. The ceramic composite containing 5 wt % ZrO2 might be nominated to be implanted material because their property is quite similar to the properties of human cortical bone.
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