溶液中吸附银(I)材料的制备

Li-ping Gao, Wenxiang Luo, Yikun Zhang, H. Shen, Chunyan Lang
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引用次数: 0

摘要

银在电子、珠宝、催化等行业的应用往往会产生大量含银废水,对周围环境和人体健康造成严重影响,而银又具有一定的经济价值。因此,如何有效地处理和回收含银废水中的Ag(?)是当前人们关注的热点问题。为了寻求高效环保的吸附剂,本文比较了纯化、热改性、酸改性和热酸改性膨润土对银的吸附效率,选择了经济合理的纯化粘土作为载体,并以水玻璃为表面活性剂,3-巯基丙基三甲氧基硅烷为改性剂,完成了改性膨润土的制备及条件优化。实验表明,在水玻璃用量为膨润土的15%、膨润土与改性剂用量为1:1、溶液pH为9、温度为45℃、改性时间为5 h的条件下,合成的巯基改性膨润土对Ag(?)具有良好的吸附性能,其吸附量可达293.7 mg·g-1。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation of Material for Adsorption Ag(I) in the Solution
The application of silver in electronics, jewelry, catalytic and other industries often produces a large amount of silver-containing wastewater, which causes serious impact to the surrounding environment and human health, while silver has a certain economic value attached to it. Therefore, how to effectively treat and recover Ag(?) from the silver-containing wastewater is a hot topic of concern at present. In order to seek an efficient and environmentally friendly adsorbent, this paper compared the adsorption efficiency of purified, thermally modified, acid modified and thermally-acid modified Bentonite on silver, selected an economical and reasonable purified clay as a carrier, and then completed the preparation of modified Bentonite as well as the optimization of conditions with sodium silicate as a surfactant and 3-mercaptopropyltrimethoxysilane as a modifier. The experiments showed that under the conditions of sodium silicate dosage of 15% of Bentonite, Bentonite and modifier dosage of 1:1, solution pH of 9, temperature of 45 °C and modification time of 5 h, the synthesized sulfhydryl modified Bentonite has good adsorption performance on Ag(?), and its adsorption capacity can reach 293.7 mg·g-1.
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