{"title":"B-O化学键长度作为寻找新的无中心硼酸盐晶体的判据","authors":"V. Atuchin, B. Kidyarov","doi":"10.1109/NLP.2011.6102667","DOIUrl":null,"url":null,"abstract":"The relation “composition - structure - NLO property” is observed for a set of >200 acentric borate crystals. The distribution of the crystals over point groups is very inhomogeneous with domination of C2v point group crystals. Acentric borates are distributed on the plane of the shortest chemical bond lengths metal-oxygen over an area, covered by a rosette of three partly crossing ellipses. The dependence of nonlinear optical susceptibility χ(2) on the shortest boron-oxygen bond length L(B-O) in borates has two maximums at L(B-O) = 136 and 148 pm.","PeriodicalId":347986,"journal":{"name":"2011 International Workshop on Nonlinear Photonics","volume":"71 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2011-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"B-O chemical bond length as a criterion for searching new acentric borate crystals\",\"authors\":\"V. Atuchin, B. Kidyarov\",\"doi\":\"10.1109/NLP.2011.6102667\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The relation “composition - structure - NLO property” is observed for a set of >200 acentric borate crystals. The distribution of the crystals over point groups is very inhomogeneous with domination of C2v point group crystals. Acentric borates are distributed on the plane of the shortest chemical bond lengths metal-oxygen over an area, covered by a rosette of three partly crossing ellipses. The dependence of nonlinear optical susceptibility χ(2) on the shortest boron-oxygen bond length L(B-O) in borates has two maximums at L(B-O) = 136 and 148 pm.\",\"PeriodicalId\":347986,\"journal\":{\"name\":\"2011 International Workshop on Nonlinear Photonics\",\"volume\":\"71 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2011-12-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2011 International Workshop on Nonlinear Photonics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/NLP.2011.6102667\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2011 International Workshop on Nonlinear Photonics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/NLP.2011.6102667","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
B-O chemical bond length as a criterion for searching new acentric borate crystals
The relation “composition - structure - NLO property” is observed for a set of >200 acentric borate crystals. The distribution of the crystals over point groups is very inhomogeneous with domination of C2v point group crystals. Acentric borates are distributed on the plane of the shortest chemical bond lengths metal-oxygen over an area, covered by a rosette of three partly crossing ellipses. The dependence of nonlinear optical susceptibility χ(2) on the shortest boron-oxygen bond length L(B-O) in borates has two maximums at L(B-O) = 136 and 148 pm.
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