Siti Hanifah Mahdiyanti, S. Tsuchikawa, K. Mitsui, L. Tolvaj
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引用次数: 0
摘要
摘要张建军,李建军,刘建军,等。2020。近红外光谱法监测杉木木材蒸煮引起的化学变化。亚洲J: 4:7 -10。杉木(Cryptomeria japonica D. Don)木材样品在90°C和110°C蒸制温度下蒸制,蒸制时间范围宽(0-20天)。采用近红外光谱法对蒸煮过程中的化学变化进行了监测。用差谱法分析了吸光度的增加和减少。在进行减法之前,为了消除光谱的平行偏移,光谱在1739 nm处归一化为一个单位。在1300 ~ 2100 nm波长范围内,蒸汽诱导的化学变化与水分的吸收和浸出物的吸收有关,尤其是酚类物质的吸收。这些化学变化被怀疑与蒸煮木材的颜色变化密切相关。蒸煮时间越长,所有木材组织中酚类化合物的含量变化越相似,从而使其颜色变化更加均匀。蒸煮造成细胞壁的水包围能力损失。这种变化在110°C时比在90°C时快得多。
Steaming-caused chemical changes of sugi (Cryptomeria japonica) wood monitored by NIR spectroscopy
Abstract. Mahdiyanti SH, Tsuchikawa S, Mitsui K, Tolvaj L. 2020. Steaming-caused chemical changes of sugi (Cryptomeria japonica) wood monitored by NIR spectroscopy. Asian J For 4: 7-10. Sugi (Cryptomeria japonica D. Don) wood samples were steamed, applying a broad range of steaming time (0-20 days) at 90 and 110°C steaming temperatures. NIR spectroscopy was used to monitor the chemical changes caused by steaming. The difference spectrum method was applied to find the absorption increases and decreases. Before the subtraction, the spectra were normalized to one unit at 1739 nm to eliminate the parallel shift of the spectra. Steam-induced chemical changes in the wavelength range of 1300-2100 nm are related to the absorption of water and the absorption of extractives, especially phenolic contents. These chemical changes are suspected to be strongly related to color changes in steamed wood. Longer duration of steaming caused phenolic compounds to change into similar contents in all wood tissues, which cause their color to change more uniformly. Steaming caused a water bounding capacity loss of the cell wall. This change was much faster at 110°C than at 90°C.