热老化交联聚乙烯电缆模型松弛过程的研究

A. Motori, G. Montanari, S. Gubanski
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引用次数: 3

摘要

本文介绍了在预处理和热老化的XLPE(交联聚乙烯)电缆模型上进行的热激放电电流(TSDC)和直流等温充放电电流测量的结果。在TSDC光谱中发现了A /spl β /弛豫,这与非晶态区玻璃橡胶转变有关;在TSDC光谱中发现了一个高温峰,可能是由于电荷极化引起的,与晶态区熔化有关。热时效过程中出现了TSDC峰,峰值在55/spl℃。等温放电电流测量也指出了这一过程,主要归因于电荷极化。建立了TSDC峰强度和温度位置的变化与时效以及其他性能(熔化焓、熔化温度、玻璃化转变温度等)的关系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of relaxation processes in thermally-aged XLPE cable models
The results of thermally stimulated discharging current (TSDC) and DC isothermal charging/discharging current measurement, performed on pretreated and thermally aged XLPE (cross-linked polyethylene) cable models, are presented. A /spl beta/ relaxation, related to the glass-rubber transition of the amorphous region, and a high-temperature peak, likely due to charge polarization and related to the melting of the crystalline region, were found in the TSDC spectra. A TSDC peak with a maximum at 55/spl deg/C appeared with thermal aging. This process was also pointed out by isothermal discharging current measurement and was mainly ascribed to charge polarization. Correlations between the changes of intensity and temperature location of TSDC peaks with aging and changes of other properties as well (melting enthalpy and temperature, glass-transition temperature, etc.) were established.<>
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