分子磁光

P. Gangopadhyay, G. Koeckelberghs, A. Persoons
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引用次数: 1

摘要

本文报道了多噻吩的磁光性质和法拉第旋转以及3-烷基噻吩的大环的最新研究。持续电流存在的假设,类似于介观金属结构中的持续电流,被认为是共轭聚合物中大法拉第旋转以及这些聚合物在低温下铁磁转变的相关机制。烷基噻吩的大环作为研究纳米级有机材料中持续电流的基本结构被提出和讨论。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Molecular magneto-optics
We report on recent studies of magneto-optic properties and Faraday rotation of polythiophenes and macrocycles of 3- alkylthiophenes. The hypothesis of the existence of persistent currents, analogous to the persistent currents in mesoscopic metal structures, is forwarded as a relevant mechanism basic to the large Faraday rotation in conjugated polymers as well as for the ferromagnetic transition in these polymers at cryogenic temperatures. Macrocycles of alkylthiophenes are presented and discussed as fundamental structures to investigate persistent currents in nanoscopic organic materials.
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