Martin H. Jones , William Levason , Charles A. McAuliffe , Stephen G. Murray , Denise M. Johns
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引用次数: 57
摘要
兼性潜在的四牙齿硫醚配体1,2-二(2-甲基硫乙基硫)乙烷(2,2,2)、1,3-二(2-甲基硫乙基硫)丙烷(2,3,2)和1,2-二(3-甲基硫丙基硫)乙烷(3,2,3)与铜(II)盐反应生成Cu2(2,2,2)Cl4、Cu3(配体)X6(配体= 2,3,2和3,2,3 X = Cl;配体= 2,2,2,3,2和3,2,3 X = Br)和Cu(配体)(ClO4)2。stoichiom -
The relationship of some copper (II) complexes of facultative tetrathioethers to the coordination environment in the “blue” copper proteins
The facultative potentially tetradentate thioether ligands 1,2-bis(2-methylthioethylthio)ethane (2,2,2), 1,3-bis(2-methylthioethylthio)propane (2,3,2) and 1,2-bis(3-methylthiopropylthio)ethane (3,2,3) react with copper(II) salts to form Cu2(2,2,2)Cl4, Cu3(ligand)X6 (ligand = 2,3,2 and 3,2,3 X = Cl; ligand = 2,2,2 2,3,2 and 3,2,3 X = Br), and Cu(ligand)(ClO4)2. The stoichiom-
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