介孔氧化钴纳米颗粒丙酮气敏性能的改进及其物理机理

Madiha Khan, Ahtisham Anjum, Muhammad Zaka, Irum M
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摘要

介孔氧化钴纳米颗粒目前在世界范围内广泛应用于各种应用。它对环境和经济都有利。本研究采用了一种经济有效的热搅拌方法制备了该材料。采用室温x射线衍射法对材料的单尖晶石结构的形成、纯度和阳离子分布进行了分析,得到中孔氧化钴纳米颗粒的晶格常数为8.23 Å。SEM和EDX检测用于研究相形成、元素含量和表面形貌。原始介孔氧化钴纳米颗粒的平均粒径为17nm。DRS测定了中孔氧化钴纳米颗粒的带隙为1.48 eV,间接带隙为2.19 eV。由于样品的介孔结构具有较大的表面积,因此样品的灵敏度更高。介孔氧化钴纳米颗粒具有更大的比表面积(59.63m2 g−1),在150℃的最佳工作温度下具有良好的丙酮气敏特性。此外,该样品对丙酮气体具有较高的稳定性和选择性。通过比较介孔氧化钴纳米颗粒对表面氧和丙酮气体吸附的敏感性,确定了气敏机理。根据结果,它是其他顶级材料中最好的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Highly Improved Acetone Gas Sensing Performance of Mesoporous Cobaltosic Oxide Nanoparticles and Physical Mechanism
Mesoporous Cobaltosic oxide nanoparticles are now widely employed in a variety of applications across the world. It is both environmentally and economically favorable. It was well prepared in this study using a cost-effective thermal stirring procedure. The X-ray diffraction method at ambient temperature was used to explain the formation of single spinel structure, purity, and cat-ion distribution of the material, and the lattice constant of mesoporous Cobaltosic oxide nanoparticles was 8.23 Å. SEM and EDX examination were used to investigate phase formation, elemental content, and surface morphology. The average particle size for primitive mesoporous Cobaltosic oxide nanoparticles is 17nm. DRS determined the band gap for mesoporous Cobaltosic oxide nanoparticles to be 1.48 eV for direct band bending and 2.19 eV for indirect band gap. The sensitivities of the sample are greater due to the mesoporous-structures with a large surface area. Mesoporous Cobaltosic oxide nanoparticles have a greater specific surface area (59.63m2 g− 1), resulting in good acetone gas sensing characteristics at the optimal working temperature of 150°C. Furthermore, the sample exhibits high stability and selectivity against acetone gas. The gas-sensing mechanism is determined by comparing the sensitivity of Mesoporous Cobaltosic oxide nanoparticles to surface oxygen and acetone gas adsorption. It is the best among the top other materials, according to the results.
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